Z-E conformational isomerism of nerol, geraniol, and their acetates

J.W. Haan, de; L.J.M. Ven, van de

doi:10.1016/S0040-4039(01)96957-6

Z-E conformational isomerism of nerol, geraniol, and their acetates

J.W. Haan, de, L.J.M. Ven, van de

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

18 Citaten (Scopus)

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Samenvatting

NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]

Originele taal-2	Engels
Pagina's (van-tot)	2703-2706
Aantal pagina's	4
Tijdschrift	Tetrahedron Letters
Volume	12
Nummer van het tijdschrift	29
DOI's	https://doi.org/10.1016/S0040-4039(01)96957-6
Status	Gepubliceerd - 1971

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abstract = "NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]",

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AU - Ven, van de, L.J.M.

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N2 - NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]

AB - NMR shift values indicate that geraniol has an E-conformation and nerol a Z-conformation. Thus, the shift reagent, tris(dipivalomethanato)-europium(III), is added to solns. of geraniol, nerol, geranyl acetate, and neryl acetate in CCl4 and the shift values of the C-4, C-5, and C-10 protons are examd. The opposite conformational assignments made by F. H. A. Rummens (1965) are discussed. [on SciFinder (R)]

U2 - 10.1016/S0040-4039(01)96957-6

DO - 10.1016/S0040-4039(01)96957-6

M3 - Article

VL - 12

SP - 2703

EP - 2706

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 29

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