Triazole-based leaving group for raft-mediated polymerization synthesized via the cu-mediated huisgen 1,3-dipolar cycloaddition reaction

N. Akeroyd, R. Pfukwa, B. Klumperman

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

24 Citaten (Scopus)
1 Downloads (Pure)

Samenvatting

A new RAFT agent leaving group based on a triazole moiety is introduced. The triazole moiety plays an active role in the stabilization of the intermediate radical, comparable to the phenyl group in a benzyl leaving group. The newly developed leaving group allows easy conjugation to a large variety of substrates where the triazole linking group is hydrolytically stable. Good control is reported in the polymerizations of vinyl acetate, N-vinylpyrrolidone, n-butyl acrylate, and styrene. The versatility of the method is exemplified by linking the triazole to a phenyl and to an oligosaccharide substrate. Overall, this new RAFT agent leaving group is a useful addition to the limited set of leaving groups reported in literature. © 2009 American Chemical Society.
Originele taal-2Engels
Pagina's (van-tot)3014-3018
TijdschriftMacromolecules
Volume42
Nummer van het tijdschrift8
DOI's
StatusGepubliceerd - 2009

Vingerafdruk Duik in de onderzoeksthema's van 'Triazole-based leaving group for raft-mediated polymerization synthesized via the cu-mediated huisgen 1,3-dipolar cycloaddition reaction'. Samen vormen ze een unieke vingerafdruk.

Citeer dit