Transport of water-glycerol mixtures in porous materials studied with NMR imaging

C.J. Kuijpers, H.P. Huinink, O.C.G. Adan, S.J.F. Erich, N. Tomozeiu

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureHoofdstukAcademicpeer review

Samenvatting

The penetration of water-glycerol mixtures in a porous material is studied by using NMR (Nuclear Magnetic Resonance) measurements in view of understanding and improving water based inks performance on paper. Al2O3 samples are used as well-defined model systems to quantify the penetration of each mixture component. We investigated the dependence of glycerol concentration in water on the penetration speed, and quantify to what extend the mixture separates in the porous material. We visualized water and glycerol as a function of time and link the behavior of this mixture to the rheological properties. Finally, we investigated the effect of pore size on the imbibition behavior. We found that water-glycerol mixtures penetrate the porous material as a single liquid in both 200 nm and 1100 nm porous Al2O3. Furthermore we showed that the imbibition process can be described by a modified version of Washburn’s equation and that the behavior can be scaled with liquid and media parameters to result in one generic curve. This implies that the complex mixture behaves as a homogeneous liquid and the sorption behavior is determined by the average viscosity and surface tension of the mixture.
Originele taal-2Nederlands
TitelComputational methods in multiphase flow VIII
RedacteurenP. Vorobieff, C.A. Brebbia, J.L. Munoz-Cobo
Plaats van productieSouthampton
UitgeverijWIT Press
Pagina's513-526
Aantal pagina's14
ISBN van elektronische versie978-1-84564-947-0
ISBN van geprinte versie978-1-84564-946-3
StatusGepubliceerd - 2015

Publicatie series

NaamWIT transactions on engineering sciences
Volume89

Trefwoorden

  • NMR imaging
  • Washburn’s equation
  • complex mixtures
  • imbibition
  • paper.
  • porous media

Citeer dit

Kuijpers, C. J., Huinink, H. P., Adan, O. C. G., Erich, S. J. F., & Tomozeiu, N. (2015). Transport of water-glycerol mixtures in porous materials studied with NMR imaging. In P. Vorobieff, C. A. Brebbia, & J. L. Munoz-Cobo (editors), Computational methods in multiphase flow VIII (blz. 513-526). (WIT transactions on engineering sciences; Vol. 89). Southampton: WIT Press.