The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy

M. Vaarkamp; J.T. Miller; F.S. Modica; G.S. Lane; D.C. Koningsberger

doi:10.1016/S0167-2991(08)64058-6

The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy

M. Vaarkamp
, J.T. Miller
, F.S. Modica
, G.S. Lane
, D.C. Koningsberger

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/Congresprocedure › Conferentiebijdrage › Academic › peer review

31 Citaten (Scopus)

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The intensity of the white line of the LII and LIII x-ray absorption edge spectra of small platinum particles increases with decreasing particle size. The combined white line intensity of the LII and LIII x-ray absorption spectra for platinum catalysts with comparable av. particle size is higher when dispersed on acidic than on neutral supports. This indicates that Pt particles are more electron deficient on acidic than on neutral supports. The propane hydrogenolysis TOF for Pt supported on g-Al2O3 or H-LTL is more than an order of magnitude higher than for Pt supported on a nonacidic K-LTL zeolite. The differences in catalytic behavior are related to differences in the d-band d. of states. [on SciFinder (R)]

Originele taal-2	Engels
Titel	New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A
Redacteuren	L. Guczi, F. Solymosi, P. Tétényi
Plaats van productie	Amsterdam
Uitgeverij	Elsevier
Pagina's	809-820
ISBN van geprinte versie	0-444-89621-X
DOI's	https://doi.org/10.1016/S0167-2991(08)64058-6
Status	Gepubliceerd - 1993
Evenement	10th International Congress on Catalysis (ICC 1992) - Budapest, Hongarije Duur: 19 jul. 1992 → 24 jul. 1992 Congresnummer: 10

Publicatie series

Naam	Studies in Surface Science and Catalysis
Nummer	Part A
Volume	75
ISSN van geprinte versie	0167-2991

Congres

Congres	10th International Congress on Catalysis (ICC 1992)
Verkorte titel	ICC 1992
Land/Regio	Hongarije
Stad	Budapest
Periode	19/07/92 → 24/07/92
Ander	International Congress on Catalysis ; 10 (Budapest) : 1992.07.19-24

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10.1016/S0167-2991(08)64058-6

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Vaarkamp, M., Miller, J. T., Modica, F. S., Lane, G. S., & Koningsberger, D. C. (1993). The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy. In L. Guczi, F. Solymosi, & P. Tétényi (editors), New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A (blz. 809-820). (Studies in Surface Science and Catalysis; Vol. 75, Nr. Part A). Elsevier. https://doi.org/10.1016/S0167-2991(08)64058-6

Vaarkamp, M. ; Miller, J.T. ; Modica, F.S. et al. / The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy. New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A. redacteur / L. Guczi ; F. Solymosi ; P. Tétényi. Amsterdam : Elsevier, 1993. blz. 809-820 (Studies in Surface Science and Catalysis; Part A).

@inproceedings{a891bd6a11304316bb57726cb18c7e8b,

title = "The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy",

abstract = "The intensity of the white line of the LII and LIII x-ray absorption edge spectra of small platinum particles increases with decreasing particle size. The combined white line intensity of the LII and LIII x-ray absorption spectra for platinum catalysts with comparable av. particle size is higher when dispersed on acidic than on neutral supports. This indicates that Pt particles are more electron deficient on acidic than on neutral supports. The propane hydrogenolysis TOF for Pt supported on g-Al2O3 or H-LTL is more than an order of magnitude higher than for Pt supported on a nonacidic K-LTL zeolite. The differences in catalytic behavior are related to differences in the d-band d. of states. [on SciFinder (R)]",

author = "M. Vaarkamp and J.T. Miller and F.S. Modica and G.S. Lane and D.C. Koningsberger",

year = "1993",

doi = "10.1016/S0167-2991(08)64058-6",

language = "English",

isbn = "0-444-89621-X",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

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pages = "809--820",

editor = "L. Guczi and F. Solymosi and P. T{\'e}t{\'e}nyi",

booktitle = "New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A",

address = "Netherlands",

note = "10th International Congress on Catalysis (ICC 1992), ICC 1992 ; Conference date: 19-07-1992 Through 24-07-1992",

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Vaarkamp, M, Miller, JT, Modica, FS, Lane, GS & Koningsberger, DC 1993, The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy. in L Guczi, F Solymosi & P Tétényi (reds.), New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A. Studies in Surface Science and Catalysis, nr. Part A, vol. 75, Elsevier, Amsterdam, blz. 809-820, 10th International Congress on Catalysis (ICC 1992), Budapest, Hongarije, 19/07/92. https://doi.org/10.1016/S0167-2991(08)64058-6

The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy. / Vaarkamp, M.; Miller, J.T.; Modica, F.S. et al.
New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A. reds. / L. Guczi; F. Solymosi; P. Tétényi. Amsterdam: Elsevier, 1993. blz. 809-820 (Studies in Surface Science and Catalysis; Vol. 75, Nr. Part A).

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/Congresprocedure › Conferentiebijdrage › Academic › peer review

TY - GEN

T1 - The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy

AU - Vaarkamp, M.

AU - Miller, J.T.

AU - Modica, F.S.

AU - Lane, G.S.

AU - Koningsberger, D.C.

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PY - 1993

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N2 - The intensity of the white line of the LII and LIII x-ray absorption edge spectra of small platinum particles increases with decreasing particle size. The combined white line intensity of the LII and LIII x-ray absorption spectra for platinum catalysts with comparable av. particle size is higher when dispersed on acidic than on neutral supports. This indicates that Pt particles are more electron deficient on acidic than on neutral supports. The propane hydrogenolysis TOF for Pt supported on g-Al2O3 or H-LTL is more than an order of magnitude higher than for Pt supported on a nonacidic K-LTL zeolite. The differences in catalytic behavior are related to differences in the d-band d. of states. [on SciFinder (R)]

AB - The intensity of the white line of the LII and LIII x-ray absorption edge spectra of small platinum particles increases with decreasing particle size. The combined white line intensity of the LII and LIII x-ray absorption spectra for platinum catalysts with comparable av. particle size is higher when dispersed on acidic than on neutral supports. This indicates that Pt particles are more electron deficient on acidic than on neutral supports. The propane hydrogenolysis TOF for Pt supported on g-Al2O3 or H-LTL is more than an order of magnitude higher than for Pt supported on a nonacidic K-LTL zeolite. The differences in catalytic behavior are related to differences in the d-band d. of states. [on SciFinder (R)]

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M3 - Conference contribution

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T3 - Studies in Surface Science and Catalysis

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EP - 820

BT - New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A

A2 - Guczi, L.

A2 - Solymosi, F.

A2 - Tétényi, P.

PB - Elsevier

CY - Amsterdam

T2 - 10th International Congress on Catalysis (ICC 1992)

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Vaarkamp M, Miller JT, Modica FS, Lane GS, Koningsberger DC. The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy. In Guczi L, Solymosi F, Tétényi P, redacteurs, New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19 - 24, 1992. Part A. Amsterdam: Elsevier. 1993. blz. 809-820. (Studies in Surface Science and Catalysis; Part A). doi: 10.1016/S0167-2991(08)64058-6

The relation between catalytic and electronic properties of supported platinum catalysts: the local density of states as determined by x-ray absorption spectroscopy

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