The influence of carbon on the adsorption of CO on a RH(100) single crystal

D.L.S. Nieskens; M.M.M. Jansen; A.P. Bavel, van; D. Curulla Ferre; J.W. Niemantsverdriet

doi:10.1039/b513233a

The influence of carbon on the adsorption of CO on a RH(100) single crystal

D.L.S. Nieskens, M.M.M. Jansen, A.P. Bavel, van, D. Curulla Ferre, J.W. Niemantsverdriet

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

21 Citaten (Scopus)

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The influence of carbon on the adsorption of CO from a Rh(100) single crystal has been studied by a combination of experimental techniques: Temperature Programmed Desorption (TPD), Low Energy Electron Diffraction (LEED), and High Resolution Electron Energy Loss Spectroscopy (HREELS). These experimental techniques were combined with a computational approach using Density Functional Theory (DFT). Using this combination of techniques, we have shown that surface carbon greatly influences adsorbed CO and we have determined the exact magnitude of this interaction. Furthermore, we have demonstrated that carbon does not remain fully on the surface; at higher coverage it diffuses partially to subsurface positions. The presence of these subsurface species significantly influences the adsorbates on the surface.

Originele taal-2	Engels
Pagina's (van-tot)	624-632
Tijdschrift	Physical Chemistry Chemical Physics
Volume	8
Nummer van het tijdschrift	5
DOI's	https://doi.org/10.1039/b513233a
Status	Gepubliceerd - 2006

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title = "The influence of carbon on the adsorption of CO on a RH(100) single crystal",

abstract = "The influence of carbon on the adsorption of CO from a Rh(100) single crystal has been studied by a combination of experimental techniques: Temperature Programmed Desorption (TPD), Low Energy Electron Diffraction (LEED), and High Resolution Electron Energy Loss Spectroscopy (HREELS). These experimental techniques were combined with a computational approach using Density Functional Theory (DFT). Using this combination of techniques, we have shown that surface carbon greatly influences adsorbed CO and we have determined the exact magnitude of this interaction. Furthermore, we have demonstrated that carbon does not remain fully on the surface; at higher coverage it diffuses partially to subsurface positions. The presence of these subsurface species significantly influences the adsorbates on the surface.",

author = "D.L.S. Nieskens and M.M.M. Jansen and {Bavel, van}, A.P. and {Curulla Ferre}, D. and J.W. Niemantsverdriet",

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doi = "10.1039/b513233a",

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AU - Nieskens, D.L.S.

AU - Jansen, M.M.M.

AU - Bavel, van, A.P.

AU - Curulla Ferre, D.

AU - Niemantsverdriet, J.W.

PY - 2006

Y1 - 2006

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AB - The influence of carbon on the adsorption of CO from a Rh(100) single crystal has been studied by a combination of experimental techniques: Temperature Programmed Desorption (TPD), Low Energy Electron Diffraction (LEED), and High Resolution Electron Energy Loss Spectroscopy (HREELS). These experimental techniques were combined with a computational approach using Density Functional Theory (DFT). Using this combination of techniques, we have shown that surface carbon greatly influences adsorbed CO and we have determined the exact magnitude of this interaction. Furthermore, we have demonstrated that carbon does not remain fully on the surface; at higher coverage it diffuses partially to subsurface positions. The presence of these subsurface species significantly influences the adsorbates on the surface.

U2 - 10.1039/b513233a

DO - 10.1039/b513233a

M3 - Article

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SN - 1463-9076

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EP - 632

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 5

ER -

The influence of carbon on the adsorption of CO on a RH(100) single crystal

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