The dissociation kinetics of NO on Rh(111) as studied by temperature programmed static secondary ion mass spectrometry and desorption

H.J. Borg; J.F.C.-J.M. Reijerse; R.A. Santen, van; J.W. Niemantsverdriet

doi:10.1063/1.467994

The dissociation kinetics of NO on Rh(111) as studied by temperature programmed static secondary ion mass spectrometry and desorption

H.J. Borg
, J.F.C.-J.M. Reijerse
, R.A. Santen, van
, J.W. Niemantsverdriet

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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Temperature programmed static secondary ion mass spectrometry (TPSSIMS) and temperature programmed desorption (TPD) have been used to study the kinetics of adsorption, dissociation, and desorption of NO on Rh(111). At 100 K, NO adsorption is molecular and proceeds via mobile precursor state kinetics with a high initial sticking probability. SSIMS indicates the presence of two distinct NO adsorption states, indicative of threefold adsorption at low coverage, and occupation of bridge sites at higher coverages. Three characteristic coverage regimes appear with respect to NO dissociation. At low coverages NO

Originele taal-2	Engels
Pagina's (van-tot)	10052-10063
Aantal pagina's	12
Tijdschrift	Journal of Chemical Physics
Volume	101
Nummer van het tijdschrift	11
DOI's	https://doi.org/10.1063/1.467994
Status	Gepubliceerd - 1994

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title = "The dissociation kinetics of NO on Rh(111) as studied by temperature programmed static secondary ion mass spectrometry and desorption",

abstract = "Temperature programmed static secondary ion mass spectrometry (TPSSIMS) and temperature programmed desorption (TPD) have been used to study the kinetics of adsorption, dissociation, and desorption of NO on Rh(111). At 100 K, NO adsorption is molecular and proceeds via mobile precursor state kinetics with a high initial sticking probability. SSIMS indicates the presence of two distinct NO adsorption states, indicative of threefold adsorption at low coverage, and occupation of bridge sites at higher coverages. Three characteristic coverage regimes appear with respect to NO dissociation. At low coverages NO",

author = "H.J. Borg and J.F.C.-J.M. Reijerse and \{Santen, van\}, R.A. and J.W. Niemantsverdriet",

year = "1994",

doi = "10.1063/1.467994",

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T1 - The dissociation kinetics of NO on Rh(111) as studied by temperature programmed static secondary ion mass spectrometry and desorption

AU - Borg, H.J.

AU - Reijerse, J.F.C.-J.M.

AU - Santen, van, R.A.

AU - Niemantsverdriet, J.W.

PY - 1994

Y1 - 1994

N2 - Temperature programmed static secondary ion mass spectrometry (TPSSIMS) and temperature programmed desorption (TPD) have been used to study the kinetics of adsorption, dissociation, and desorption of NO on Rh(111). At 100 K, NO adsorption is molecular and proceeds via mobile precursor state kinetics with a high initial sticking probability. SSIMS indicates the presence of two distinct NO adsorption states, indicative of threefold adsorption at low coverage, and occupation of bridge sites at higher coverages. Three characteristic coverage regimes appear with respect to NO dissociation. At low coverages NO

AB - Temperature programmed static secondary ion mass spectrometry (TPSSIMS) and temperature programmed desorption (TPD) have been used to study the kinetics of adsorption, dissociation, and desorption of NO on Rh(111). At 100 K, NO adsorption is molecular and proceeds via mobile precursor state kinetics with a high initial sticking probability. SSIMS indicates the presence of two distinct NO adsorption states, indicative of threefold adsorption at low coverage, and occupation of bridge sites at higher coverages. Three characteristic coverage regimes appear with respect to NO dissociation. At low coverages NO

U2 - 10.1063/1.467994

DO - 10.1063/1.467994

M3 - Article

SN - 0021-9606

VL - 101

SP - 10052

EP - 10063

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 11

ER -

The dissociation kinetics of NO on Rh(111) as studied by temperature programmed static secondary ion mass spectrometry and desorption

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