Temperature and growth-rate effects on the hydrogen incorporation in a-Si:H

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Samenvatting

Hydrogen incorporation in amorphous hydrogenated silicon produced by the expanding thermal plasma is investigated as a function of substrate temperature at three different deposition rates of 0.3, 3 and 11 nm/s. The increase of the refractive index with increasing substrate temperature is attributed to decreasing hydrogen concentration. The latter result is explained by a model which assumes a thermally activated hydrogen cross-linking step immediately after the chemisorption of a silyl radical. The activation energy for this process is about 150 meV. For growth rates larger than 1 nm/s the hydrogen content is significantly growth-rate dependent.
Originele taal-2Engels
Pagina's (van-tot)133-137
Aantal pagina's5
TijdschriftJournal of Non-Crystalline Solids
Volume227-230
Nummer van het tijdschrift1
DOI's
StatusGepubliceerd - 1998

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