Tailored bimodal ultra-high molecular weight polyethylene particles

Sarah Lafleur, Romain Berthoud, Richard Ensinck, Astrid Cordier, Gert De Cremer, An Philippaerts, Kees Bastiaansen, Tigran Margossian, John R. Severn

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

2 Citaties (Scopus)

Uittreksel

A single molecular catalyst system supported on MgCl2 has been developed and combined with a simple two-stage fed-batch polymerization process to produce tailored bimodal polyethylene reactor blend particles of UHMWPE. By varying and controlling the process conditions in the first stage and second stage, bimodal HMWPE:UHMWPE reactor particles are obtained with independent control over the individual molar masses, the mass ratio of the HMWPE and UHMWPE components, and the reactor powder particle size. This allows multidimensional control over the individual UHMWPE reactor particle properties.

TaalEngels
Pagina's1645-1656
Aantal pagina's12
TijdschriftJournal of Polymer Science, Part A: Polymer Chemistry
Volume56
Nummer van het tijdschrift15
DOI's
StatusGepubliceerd - 1 aug 2018

Vingerafdruk

Ultrahigh molecular weight polyethylenes
Molar mass
Polyethylene
Powders
Polyethylenes
Particle size
Polymerization
Catalysts
ultra-high molecular weight polyethylene

Trefwoorden

    Citeer dit

    Lafleur, S., Berthoud, R., Ensinck, R., Cordier, A., De Cremer, G., Philippaerts, A., ... Severn, J. R. (2018). Tailored bimodal ultra-high molecular weight polyethylene particles. Journal of Polymer Science, Part A: Polymer Chemistry, 56(15), 1645-1656. DOI: 10.1002/pola.29037
    Lafleur, Sarah ; Berthoud, Romain ; Ensinck, Richard ; Cordier, Astrid ; De Cremer, Gert ; Philippaerts, An ; Bastiaansen, Kees ; Margossian, Tigran ; Severn, John R./ Tailored bimodal ultra-high molecular weight polyethylene particles. In: Journal of Polymer Science, Part A: Polymer Chemistry. 2018 ; Vol. 56, Nr. 15. blz. 1645-1656
    @article{6763887150a94b3186faed2d7e17dfff,
    title = "Tailored bimodal ultra-high molecular weight polyethylene particles",
    abstract = "A single molecular catalyst system supported on MgCl2 has been developed and combined with a simple two-stage fed-batch polymerization process to produce tailored bimodal polyethylene reactor blend particles of UHMWPE. By varying and controlling the process conditions in the first stage and second stage, bimodal HMWPE:UHMWPE reactor particles are obtained with independent control over the individual molar masses, the mass ratio of the HMWPE and UHMWPE components, and the reactor powder particle size. This allows multidimensional control over the individual UHMWPE reactor particle properties.",
    keywords = "(post)metallocene, bimodal, polyethylene, supported catalyst, UHMWPE",
    author = "Sarah Lafleur and Romain Berthoud and Richard Ensinck and Astrid Cordier and {De Cremer}, Gert and An Philippaerts and Kees Bastiaansen and Tigran Margossian and Severn, {John R.}",
    year = "2018",
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    Lafleur, S, Berthoud, R, Ensinck, R, Cordier, A, De Cremer, G, Philippaerts, A, Bastiaansen, K, Margossian, T & Severn, JR 2018, 'Tailored bimodal ultra-high molecular weight polyethylene particles' Journal of Polymer Science, Part A: Polymer Chemistry, vol. 56, nr. 15, blz. 1645-1656. DOI: 10.1002/pola.29037

    Tailored bimodal ultra-high molecular weight polyethylene particles. / Lafleur, Sarah; Berthoud, Romain; Ensinck, Richard; Cordier, Astrid; De Cremer, Gert; Philippaerts, An; Bastiaansen, Kees; Margossian, Tigran; Severn, John R.

    In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 56, Nr. 15, 01.08.2018, blz. 1645-1656.

    Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

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    AU - Lafleur,Sarah

    AU - Berthoud,Romain

    AU - Ensinck,Richard

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    AU - De Cremer,Gert

    AU - Philippaerts,An

    AU - Bastiaansen,Kees

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    AU - Severn,John R.

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    Y1 - 2018/8/1

    N2 - A single molecular catalyst system supported on MgCl2 has been developed and combined with a simple two-stage fed-batch polymerization process to produce tailored bimodal polyethylene reactor blend particles of UHMWPE. By varying and controlling the process conditions in the first stage and second stage, bimodal HMWPE:UHMWPE reactor particles are obtained with independent control over the individual molar masses, the mass ratio of the HMWPE and UHMWPE components, and the reactor powder particle size. This allows multidimensional control over the individual UHMWPE reactor particle properties.

    AB - A single molecular catalyst system supported on MgCl2 has been developed and combined with a simple two-stage fed-batch polymerization process to produce tailored bimodal polyethylene reactor blend particles of UHMWPE. By varying and controlling the process conditions in the first stage and second stage, bimodal HMWPE:UHMWPE reactor particles are obtained with independent control over the individual molar masses, the mass ratio of the HMWPE and UHMWPE components, and the reactor powder particle size. This allows multidimensional control over the individual UHMWPE reactor particle properties.

    KW - (post)metallocene

    KW - bimodal

    KW - polyethylene

    KW - supported catalyst

    KW - UHMWPE

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    Lafleur S, Berthoud R, Ensinck R, Cordier A, De Cremer G, Philippaerts A et al. Tailored bimodal ultra-high molecular weight polyethylene particles. Journal of Polymer Science, Part A: Polymer Chemistry. 2018 aug 1;56(15):1645-1656. Beschikbaar vanaf, DOI: 10.1002/pola.29037