Synthesis of an isocyanate-functionalized terpyridine as building block for metallo-supramolecular polymers

R. Hoogenboom, P.R. Andres, G. Kickelbick, U.S. Schubert

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

10 Citaten (Scopus)
2 Downloads (Pure)

Samenvatting

An amino-pentyl-functionalized terpyridine was converted to the corresponding isocyanate, which could be crystallized and studied by X-ray diffraction. The isocyanate-functionalized terpyridine was utilized as a reactive building block for the formation of a metal-coordinating polymer by reacting it under mild ­conditions with a hydroxy functionalized poly(THF). GPC characterization and UV-titration proved successful functionalization and complexation. Secondly, the isocyanate building block was successfully utilized for the formation of a metal coordinating ­compound with two different binding moieties as was proven by 1H NMR spectroscopy.
Originele taal-2Engels
Pagina's (van-tot)1779-1783
TijdschriftSynlett
Nummer van het tijdschrift10
DOI's
StatusGepubliceerd - 2004

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