Synthesis and micellization of coil-rod-coil Ruthenium(II) terpyridine assemblies

M. Chiper; A. Winter; R. Hoogenboom; D.A.M. Egbe; D. Wouters; S. Höppener; C.A. Fustin; J.M.W. Gohy; U.S. Schubert

doi:10.1021/ma801217v

Synthesis and micellization of coil-rod-coil Ruthenium(II) terpyridine assemblies

M. Chiper, A. Winter, R. Hoogenboom, D.A.M. Egbe, D. Wouters, S. Höppener, C.A. Fustin, J.M.W. Gohy, U.S. Schubert

Chemical Engineering and Chemistry

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

28 Citaten (Scopus)

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Four different coil-rod-coil metallo-supramol. amphiphilic copolymers have been synthesized via Ru(II) terpyridine complexation, using monoterpyridine end-functionalized poly(ethylene glycol) as hydrophilic block A and different rigid-rod conjugated ditopic terpyridyl ligands as hydrophobic segment B. Those structures are reminiscent of ABA triblock copolymers. Herein, we report for the first time the synthesis and characterization as well as the photophys. and electrochem. properties of these novel Ru(II) ABA assemblies. The aq. self-assembly of these synthesized materials was studied by cryo-transmission electron microscopy and dynamic light scattering, demonstrating a significant influence of the various middle segments B on the size of the obtained micelles. [on SciFinder (R)]

Originele taal-2	Engels
Pagina's (van-tot)	8823-8831
Tijdschrift	Macromolecules
Volume	41
Nummer van het tijdschrift	22
DOI's	https://doi.org/10.1021/ma801217v
Status	Gepubliceerd - 2008

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title = "Synthesis and micellization of coil-rod-coil Ruthenium(II) terpyridine assemblies",

abstract = "Four different coil-rod-coil metallo-supramol. amphiphilic copolymers have been synthesized via Ru(II) terpyridine complexation, using monoterpyridine end-functionalized poly(ethylene glycol) as hydrophilic block A and different rigid-rod conjugated ditopic terpyridyl ligands as hydrophobic segment B. Those structures are reminiscent of ABA triblock copolymers. Herein, we report for the first time the synthesis and characterization as well as the photophys. and electrochem. properties of these novel Ru(II) ABA assemblies. The aq. self-assembly of these synthesized materials was studied by cryo-transmission electron microscopy and dynamic light scattering, demonstrating a significant influence of the various middle segments B on the size of the obtained micelles. [on SciFinder (R)]",

author = "M. Chiper and A. Winter and R. Hoogenboom and D.A.M. Egbe and D. Wouters and S. H{\"o}ppener and C.A. Fustin and J.M.W. Gohy and U.S. Schubert",

year = "2008",

doi = "10.1021/ma801217v",

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T1 - Synthesis and micellization of coil-rod-coil Ruthenium(II) terpyridine assemblies

AU - Chiper, M.

AU - Winter, A.

AU - Hoogenboom, R.

AU - Egbe, D.A.M.

AU - Wouters, D.

AU - Höppener, S.

AU - Fustin, C.A.

AU - Gohy, J.M.W.

AU - Schubert, U.S.

PY - 2008

Y1 - 2008

N2 - Four different coil-rod-coil metallo-supramol. amphiphilic copolymers have been synthesized via Ru(II) terpyridine complexation, using monoterpyridine end-functionalized poly(ethylene glycol) as hydrophilic block A and different rigid-rod conjugated ditopic terpyridyl ligands as hydrophobic segment B. Those structures are reminiscent of ABA triblock copolymers. Herein, we report for the first time the synthesis and characterization as well as the photophys. and electrochem. properties of these novel Ru(II) ABA assemblies. The aq. self-assembly of these synthesized materials was studied by cryo-transmission electron microscopy and dynamic light scattering, demonstrating a significant influence of the various middle segments B on the size of the obtained micelles. [on SciFinder (R)]

AB - Four different coil-rod-coil metallo-supramol. amphiphilic copolymers have been synthesized via Ru(II) terpyridine complexation, using monoterpyridine end-functionalized poly(ethylene glycol) as hydrophilic block A and different rigid-rod conjugated ditopic terpyridyl ligands as hydrophobic segment B. Those structures are reminiscent of ABA triblock copolymers. Herein, we report for the first time the synthesis and characterization as well as the photophys. and electrochem. properties of these novel Ru(II) ABA assemblies. The aq. self-assembly of these synthesized materials was studied by cryo-transmission electron microscopy and dynamic light scattering, demonstrating a significant influence of the various middle segments B on the size of the obtained micelles. [on SciFinder (R)]

U2 - 10.1021/ma801217v

DO - 10.1021/ma801217v

M3 - Article

SN - 0024-9297

VL - 41

SP - 8823

EP - 8831

JO - Macromolecules

JF - Macromolecules

IS - 22

ER -

Synthesis and micellization of coil-rod-coil Ruthenium(II) terpyridine assemblies

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