Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides

P.J.M. Stals; P.A. Korevaar; M.A.J. Gillissen; T.F.A. Greef, de; C.F.C. Fitie; R.P. Sijbesma; A.R.A. Palmans; E.W. Meijer

doi:10.1002/anie.201204727

Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides

P.J.M. Stals, P.A. Korevaar, M.A.J. Gillissen, T.F.A. Greef, de, C.F.C. Fitie, R.P. Sijbesma, A.R.A. Palmans, E.W. Meijer

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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The interplay of two subsequent aggregation processes results in a symmetry-breaking phenomenon in an achiral self-assembling system. Partially fluorinated benzene-1,3,5-tricarboxamide molecules self-assemble into a racemic mixture of one-dimensional P- and M-helical aggregates, followed by bundling into optically active higher-order aggregates or fibers (see picture).

Originele taal-2	Engels
Pagina's (van-tot)	11297-11301
Tijdschrift	Angewandte Chemie - International Edition
Volume	51
Nummer van het tijdschrift	45
DOI's	https://doi.org/10.1002/anie.201204727
Status	Gepubliceerd - 2012

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10.1002/anie.201204727

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title = "Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides",

abstract = "The interplay of two subsequent aggregation processes results in a symmetry-breaking phenomenon in an achiral self-assembling system. Partially fluorinated benzene-1,3,5-tricarboxamide molecules self-assemble into a racemic mixture of one-dimensional P- and M-helical aggregates, followed by bundling into optically active higher-order aggregates or fibers (see picture).",

author = "P.J.M. Stals and P.A. Korevaar and M.A.J. Gillissen and {Greef, de}, T.F.A. and C.F.C. Fitie and R.P. Sijbesma and A.R.A. Palmans and E.W. Meijer",

year = "2012",

doi = "10.1002/anie.201204727",

language = "English",

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AU - Stals, P.J.M.

AU - Korevaar, P.A.

AU - Gillissen, M.A.J.

AU - Greef, de, T.F.A.

AU - Fitie, C.F.C.

AU - Sijbesma, R.P.

AU - Palmans, A.R.A.

AU - Meijer, E.W.

PY - 2012

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N2 - The interplay of two subsequent aggregation processes results in a symmetry-breaking phenomenon in an achiral self-assembling system. Partially fluorinated benzene-1,3,5-tricarboxamide molecules self-assemble into a racemic mixture of one-dimensional P- and M-helical aggregates, followed by bundling into optically active higher-order aggregates or fibers (see picture).

AB - The interplay of two subsequent aggregation processes results in a symmetry-breaking phenomenon in an achiral self-assembling system. Partially fluorinated benzene-1,3,5-tricarboxamide molecules self-assemble into a racemic mixture of one-dimensional P- and M-helical aggregates, followed by bundling into optically active higher-order aggregates or fibers (see picture).

U2 - 10.1002/anie.201204727

DO - 10.1002/anie.201204727

M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Symmetry breaking in the self-assembly of partially fluorinated benzene-1,3,5-tricarboxamides

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