Strong decrease in viscosity of nanoparticle-filled polymer melts through selective adsorption

S.H. Jain, J.G.P. Goossens, G.W.M. Peters, M. Duin, van, P.J. Lemstra

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

169 Citaten (Scopus)
3 Downloads (Pure)

Samenvatting

The melt viscosity of poly(propylene) is found to reduce dramatically through the addition of a minute amount of silica nanoparticles. We attribute this unique effect to "selective adsorption of high molar mass polymer chains" on the surface of the nanofillers. This represents a paradigm shift regarding commonly-accepted relations between the molar mass and viscosity of molten polymers. This strong viscosity decrease provides major advantages for polymer processing and materials with improved properties are obtained.
Originele taal-2Engels
Pagina's (van-tot)1848-1854
TijdschriftSoft Matter
Volume4
Nummer van het tijdschrift9
DOI's
StatusGepubliceerd - 2008

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