Side-chain-functionalized polyacetylenes, 1 - Liquid crystalline and stereomutational properties

A.P.H.J. Schenning; M. Fransen; E.W. Meijer

doi:10.1002/1521-3927(20020301)23:4<265::AID-MARC265>3.0.CO;2-5

Side-chain-functionalized polyacetylenes, 1 - Liquid crystalline and stereomutational properties

A.P.H.J. Schenning, M. Fransen, E.W. Meijer

Macromolecular and Organic Chemistry

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

69 Citaten (Scopus)

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Communication: Stereospecific polymerizations of functionalized acetylenes were successfully performed using a Rh complex as the catalyst and triethylamine as a base yielding poly(3.4,5-tridodecyloxyphenylacetylene) (Poly5) and poly[3, 4, 5-tris((S)-3, 7-dimethyloctyloxy)phenylacetylene] (Poly6). PolyS and Poly6 are liquid crystalline with presumably a bilayer-type architecture in which the mesogens are arranged in an antiparallel overlapping interdigitated manner. Poly6 showed unusual thermal stereomutation in solution in a very narrow temperature range

Originele taal-2	Engels
Pagina's (van-tot)	266-270
Aantal pagina's	4
Tijdschrift	Macromolecular Rapid Communications
Volume	23
Nummer van het tijdschrift	4
DOI's	https://doi.org/10.1002/1521-3927(20020301)23:4<265::AID-MARC265>3.0.CO;2-5
Status	Gepubliceerd - 2002

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abstract = "Communication: Stereospecific polymerizations of functionalized acetylenes were successfully performed using a Rh complex as the catalyst and triethylamine as a base yielding poly(3.4,5-tridodecyloxyphenylacetylene) (Poly5) and poly[3, 4, 5-tris((S)-3, 7-dimethyloctyloxy)phenylacetylene] (Poly6). PolyS and Poly6 are liquid crystalline with presumably a bilayer-type architecture in which the mesogens are arranged in an antiparallel overlapping interdigitated manner. Poly6 showed unusual thermal stereomutation in solution in a very narrow temperature range",

author = "A.P.H.J. Schenning and M. Fransen and E.W. Meijer",

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T1 - Side-chain-functionalized polyacetylenes, 1 - Liquid crystalline and stereomutational properties

AU - Schenning, A.P.H.J.

AU - Fransen, M.

AU - Meijer, E.W.

PY - 2002

Y1 - 2002

N2 - Communication: Stereospecific polymerizations of functionalized acetylenes were successfully performed using a Rh complex as the catalyst and triethylamine as a base yielding poly(3.4,5-tridodecyloxyphenylacetylene) (Poly5) and poly[3, 4, 5-tris((S)-3, 7-dimethyloctyloxy)phenylacetylene] (Poly6). PolyS and Poly6 are liquid crystalline with presumably a bilayer-type architecture in which the mesogens are arranged in an antiparallel overlapping interdigitated manner. Poly6 showed unusual thermal stereomutation in solution in a very narrow temperature range

AB - Communication: Stereospecific polymerizations of functionalized acetylenes were successfully performed using a Rh complex as the catalyst and triethylamine as a base yielding poly(3.4,5-tridodecyloxyphenylacetylene) (Poly5) and poly[3, 4, 5-tris((S)-3, 7-dimethyloctyloxy)phenylacetylene] (Poly6). PolyS and Poly6 are liquid crystalline with presumably a bilayer-type architecture in which the mesogens are arranged in an antiparallel overlapping interdigitated manner. Poly6 showed unusual thermal stereomutation in solution in a very narrow temperature range

U2 - 10.1002/1521-3927(20020301)23:4<265::AID-MARC265>3.0.CO;2-5

DO - 10.1002/1521-3927(20020301)23:4<265::AID-MARC265>3.0.CO;2-5

M3 - Article

SN - 1022-1336

VL - 23

SP - 266

EP - 270

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 4

ER -

Side-chain-functionalized polyacetylenes, 1 - Liquid crystalline and stereomutational properties

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