Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

Miao Yu; Nicolo Tormene; Aleksei  Bolshakov; Brahim Mezari; Anna Liutkova; Nikolay Kosinov; Emiel J.M. Hensen

doi:10.1039/D1CC00397F

Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

Miao Yu, Nicolo Tormene, Aleksei Bolshakov, Brahim Mezari, Anna Liutkova, Nikolay Kosinov (Corresponding author), Emiel J.M. Hensen (Corresponding author)

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.

Originele taal-2	Engels
Pagina's (van-tot)	3323-3326
Aantal pagina's	4
Tijdschrift	Chemical Communications, ChemComm
Volume	57
Nummer van het tijdschrift	27
DOI's	https://doi.org/10.1039/D1CC00397F
Status	Gepubliceerd - 7 apr. 2021

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10.1039/D1CC00397F

published versionDefinitieve gepubliceerde versie, 2,89 MBLicentie: CC BY

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abstract = "A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.",

author = "Miao Yu and Nicolo Tormene and Aleksei Bolshakov and Brahim Mezari and Anna Liutkova and Nikolay Kosinov and Hensen, {Emiel J.M.}",

year = "2021",

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doi = "10.1039/D1CC00397F",

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T1 - Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

AU - Yu, Miao

AU - Tormene, Nicolo

AU - Bolshakov, Aleksei

AU - Mezari, Brahim

AU - Liutkova, Anna

AU - Kosinov, Nikolay

AU - Hensen, Emiel J.M.

PY - 2021/4/7

Y1 - 2021/4/7

N2 - A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.

AB - A methanethiol-to-olefins (MtTO) equivalent of methanol-to-olefins (MTO) chemistry is demonstrated. CH3SH can be converted to ethylene and propylene in a similar manner as CH3OH over SSZ-13 zeolite involving a hydrocarbon pool mechansim. Methylated aromatic intermediates were identified by 13C NMR analysis. Comparison of MtTO and MTO chemistry provides clues about the mechanism of C–C bond formation and catalyst deactivation.

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U2 - 10.1039/D1CC00397F

DO - 10.1039/D1CC00397F

M3 - Article

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EP - 3326

JO - Chemical Communications, ChemComm

JF - Chemical Communications, ChemComm

IS - 27

ER -

Selective Methanethiol-to-Olefins Conversion over HSSZ-13 Zeolite’

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