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Room temperature synthesized solid solution AuFe nanoparticles and their transformation into Au/Fe Janus nanocrystals

  • Maria V. Efremova (Corresponding author)
  • , Marina Spasova
  • , Markus Heidelmann
  • , Ivan S. Grebennikov
  • , Zi An Li
  • , Anastasiia S. Garanina
  • , Iana O. Tcareva
  • , Alexander G. Savchenko
  • , Michael Farle
  • , Natalia L. Klyachko
  • , Alexander G. Majouga
  • , Ulf Wiedwald

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

Samenvatting

Solid solution AuFe nanoparticles were synthesized for the first time under ambient conditions by an adapted method previously established for the Fe3O4-Au core-shell morphology. These AuFe particles preserved the fcc structure of Au incorporated with paramagnetic Fe atoms. The metastable AuFe can be segregated by transformation into Janus Au/Fe particles with bcc Fe and fcc Au upon annealing. The ferromagnetic Fe was epitaxially grown on low index fcc Au planes. This preparation route delivers new perspective materials for magnetoplasmonics and biomedical applications and suggests the reconsideration of existing protocols for magnetite-gold core-shell synthesis.

Originele taal-2Engels
Pagina's (van-tot)10402-10413
Aantal pagina's12
TijdschriftNanoscale
Volume13
Nummer van het tijdschrift23
DOI's
StatusGepubliceerd - 21 jun 2021
Extern gepubliceerdJa

Bibliografische nota

Publisher Copyright:
© The Royal Society of Chemistry.

Financiering

M. V. E. gratefully acknowledges the support from the Humboldt Research Fellowship for Postdoctoral Researchers provided by the Alexander von Humboldt Foundation and the support from the Add-on Fellowship for Interdisciplinary Life Science provided by the Joachim Herz Foundation. N. L. K. gratefully acknowledges the support from the Russian Foundation for Basic Research, grant number 18-29-09154.

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