Rh-catalyzed linear hydroformylation of styrene

E.H. Boymans; M.C.C. Janssen; C. Mueller; M. Lutz; D. Vogt

doi:10.1039/C2DT31738A

Rh-catalyzed linear hydroformylation of styrene

E.H. Boymans
, M.C.C. Janssen
, C. Mueller
, M. Lutz
, D. Vogt

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

39 Citaten (Scopus)

Samenvatting

Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldehyde. An inversion of regioselectivity can be achieved using strong p-acceptor ligands. Binaphthol-based diphosphite and bis(dipyrrolyl-phosphorodiamidite) ligands were applied in the Rh-catalyzed hydroformylation of styrene. High selectivities up to 83% of 3-phenylpropanal were obtained with 1,1-bi-2-naphthol-based bis(dipyrrolyl-phosphorodiamidite) with virtually no hydrogenation to ethyl benzene. The coordination chemistry of those ligands towards Rh(I) was investigated spectroscopically and structurally.

Originele taal-2	Engels
Pagina's (van-tot)	137-142
Aantal pagina's	6
Tijdschrift	Dalton Transactions
Volume	42
DOI's	https://doi.org/10.1039/C2DT31738A
Status	Gepubliceerd - 2012

Toegang tot document

10.1039/C2DT31738A

Citeer dit

@article{5028ab5fc0cf493184e83963270d1187,

title = "Rh-catalyzed linear hydroformylation of styrene",

abstract = "Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldehyde. An inversion of regioselectivity can be achieved using strong p-acceptor ligands. Binaphthol-based diphosphite and bis(dipyrrolyl-phosphorodiamidite) ligands were applied in the Rh-catalyzed hydroformylation of styrene. High selectivities up to 83\% of 3-phenylpropanal were obtained with 1,1-bi-2-naphthol-based bis(dipyrrolyl-phosphorodiamidite) with virtually no hydrogenation to ethyl benzene. The coordination chemistry of those ligands towards Rh(I) was investigated spectroscopically and structurally.",

author = "E.H. Boymans and M.C.C. Janssen and C. Mueller and M. Lutz and D. Vogt",

year = "2012",

doi = "10.1039/C2DT31738A",

language = "English",

volume = "42",

pages = "137--142",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Rh-catalyzed linear hydroformylation of styrene

AU - Boymans, E.H.

AU - Janssen, M.C.C.

AU - Mueller, C.

AU - Lutz, M.

AU - Vogt, D.

PY - 2012

Y1 - 2012

N2 - Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldehyde. An inversion of regioselectivity can be achieved using strong p-acceptor ligands. Binaphthol-based diphosphite and bis(dipyrrolyl-phosphorodiamidite) ligands were applied in the Rh-catalyzed hydroformylation of styrene. High selectivities up to 83% of 3-phenylpropanal were obtained with 1,1-bi-2-naphthol-based bis(dipyrrolyl-phosphorodiamidite) with virtually no hydrogenation to ethyl benzene. The coordination chemistry of those ligands towards Rh(I) was investigated spectroscopically and structurally.

AB - Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the branched, chiral aldehyde. An inversion of regioselectivity can be achieved using strong p-acceptor ligands. Binaphthol-based diphosphite and bis(dipyrrolyl-phosphorodiamidite) ligands were applied in the Rh-catalyzed hydroformylation of styrene. High selectivities up to 83% of 3-phenylpropanal were obtained with 1,1-bi-2-naphthol-based bis(dipyrrolyl-phosphorodiamidite) with virtually no hydrogenation to ethyl benzene. The coordination chemistry of those ligands towards Rh(I) was investigated spectroscopically and structurally.

U2 - 10.1039/C2DT31738A

DO - 10.1039/C2DT31738A

M3 - Article

SN - 1477-9226

VL - 42

SP - 137

EP - 142

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Rh-catalyzed linear hydroformylation of styrene

Samenvatting

Toegang tot document

Vingerafdruk

Citeer dit