Reversible polymers from self-complementary monomers, using quadruple hydrogen bonding

R.P. Sijbesma, F.H. Beijer, L. Brunsveld, B.J.B. Folmer, J.H.K.K. Hirschberg, R.F.M. Lange, J.K.L. Lowe, E.W. Meijer

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

1639 Citaties (Scopus)
66 Downloads (Pure)

Uittreksel

Units of 2-ureido-4-pyrimidone that dimerize strongly in a self-complementary array of four cooperative hydrogen bonds were used as the assocg. end group in reversible self-assembling polymer systems. The unidirectional design of the binding sites prevents uncontrolled multidirectional assocn. or gelation. Linear polymers and reversible networks were formed from monomers with two and three binding sites, resp. The thermal and environmental control over lifetime and bond strength makes many properties, such as viscosity, chain length, and compn., tunable in a way not accessible to traditional polymers. Hence, polymer networks with thermodynamically controlled architectures can be formed, for use in, for example, coatings and hot melts, where a reversible, strongly temp.-dependent rheol. is highly advantageous
Originele taal-2Engels
Pagina's (van-tot)1601-1604
TijdschriftScience
Volume278
Nummer van het tijdschrift5343
DOI's
StatusGepubliceerd - 1997

Vingerafdruk

Hydrogen bonds
Polymers
Monomers
Binding Sites
Gelation
Chain length
Viscosity
Coatings

Citeer dit

Sijbesma, R.P. ; Beijer, F.H. ; Brunsveld, L. ; Folmer, B.J.B. ; Hirschberg, J.H.K.K. ; Lange, R.F.M. ; Lowe, J.K.L. ; Meijer, E.W. / Reversible polymers from self-complementary monomers, using quadruple hydrogen bonding. In: Science. 1997 ; Vol. 278, Nr. 5343. blz. 1601-1604.
@article{433d6a92eb33477fb21b5b6311426319,
title = "Reversible polymers from self-complementary monomers, using quadruple hydrogen bonding",
abstract = "Units of 2-ureido-4-pyrimidone that dimerize strongly in a self-complementary array of four cooperative hydrogen bonds were used as the assocg. end group in reversible self-assembling polymer systems. The unidirectional design of the binding sites prevents uncontrolled multidirectional assocn. or gelation. Linear polymers and reversible networks were formed from monomers with two and three binding sites, resp. The thermal and environmental control over lifetime and bond strength makes many properties, such as viscosity, chain length, and compn., tunable in a way not accessible to traditional polymers. Hence, polymer networks with thermodynamically controlled architectures can be formed, for use in, for example, coatings and hot melts, where a reversible, strongly temp.-dependent rheol. is highly advantageous",
author = "R.P. Sijbesma and F.H. Beijer and L. Brunsveld and B.J.B. Folmer and J.H.K.K. Hirschberg and R.F.M. Lange and J.K.L. Lowe and E.W. Meijer",
year = "1997",
doi = "10.1126/science.278.5343.1601",
language = "English",
volume = "278",
pages = "1601--1604",
journal = "Science",
issn = "0036-8075",
publisher = "American Association for the Advancement of Science (AAAS)",
number = "5343",

}

Reversible polymers from self-complementary monomers, using quadruple hydrogen bonding. / Sijbesma, R.P.; Beijer, F.H.; Brunsveld, L.; Folmer, B.J.B.; Hirschberg, J.H.K.K.; Lange, R.F.M.; Lowe, J.K.L.; Meijer, E.W.

In: Science, Vol. 278, Nr. 5343, 1997, blz. 1601-1604.

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

TY - JOUR

T1 - Reversible polymers from self-complementary monomers, using quadruple hydrogen bonding

AU - Sijbesma, R.P.

AU - Beijer, F.H.

AU - Brunsveld, L.

AU - Folmer, B.J.B.

AU - Hirschberg, J.H.K.K.

AU - Lange, R.F.M.

AU - Lowe, J.K.L.

AU - Meijer, E.W.

PY - 1997

Y1 - 1997

N2 - Units of 2-ureido-4-pyrimidone that dimerize strongly in a self-complementary array of four cooperative hydrogen bonds were used as the assocg. end group in reversible self-assembling polymer systems. The unidirectional design of the binding sites prevents uncontrolled multidirectional assocn. or gelation. Linear polymers and reversible networks were formed from monomers with two and three binding sites, resp. The thermal and environmental control over lifetime and bond strength makes many properties, such as viscosity, chain length, and compn., tunable in a way not accessible to traditional polymers. Hence, polymer networks with thermodynamically controlled architectures can be formed, for use in, for example, coatings and hot melts, where a reversible, strongly temp.-dependent rheol. is highly advantageous

AB - Units of 2-ureido-4-pyrimidone that dimerize strongly in a self-complementary array of four cooperative hydrogen bonds were used as the assocg. end group in reversible self-assembling polymer systems. The unidirectional design of the binding sites prevents uncontrolled multidirectional assocn. or gelation. Linear polymers and reversible networks were formed from monomers with two and three binding sites, resp. The thermal and environmental control over lifetime and bond strength makes many properties, such as viscosity, chain length, and compn., tunable in a way not accessible to traditional polymers. Hence, polymer networks with thermodynamically controlled architectures can be formed, for use in, for example, coatings and hot melts, where a reversible, strongly temp.-dependent rheol. is highly advantageous

U2 - 10.1126/science.278.5343.1601

DO - 10.1126/science.278.5343.1601

M3 - Article

VL - 278

SP - 1601

EP - 1604

JO - Science

JF - Science

SN - 0036-8075

IS - 5343

ER -