Reactions of polypeptide esters in the solid state. II : a few cases of prevailing polycondensation : remarks concerning the reaction mechanism

L.A.A.E. Sluyterman, M. Kooistra

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9 Citaten (Scopus)

Samenvatting

When tetraglycine methyl ester is heated at 185° C in the solid state or at 100° C dissolved in methanol, polymers containing small amounts of sarcosyl-units are formed. An induction period occurs only under the first mentioned conditions. Also polymers obtained by heating triglycine methyl ester at 100°–100° C partly consisted of sarcosyl-units. Some of the phenomena described in this and the preceding part1) are believed to be due to rigidity of the crystal lattice.
Originele taal-2Engels
Pagina's (van-tot)277-284
TijdschriftRecueil des Travaux Chimiques des Pays-Bas
Volume71
Nummer van het tijdschrift3
DOI's
StatusGepubliceerd - 1952

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