Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers

Dirk Jan Mulder; Ting Liang; Yifei Xu; Jeroen ter Schiphorst; Luc M.W. Scheres; Bernette M. Oosterlaken; Zandrie Borneman; Kitty Nijmeijer; Albertus P.H.J. Schenning

doi:10.1039/c8tc00857d

Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers

Dirk Jan Mulder, Ting Liang, Yifei Xu, Jeroen ter Schiphorst, Luc M.W. Scheres, Bernette M. Oosterlaken, Zandrie Borneman, Kitty Nijmeijer, Albertus P.H.J. Schenning

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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The fabrication of a cationic nanoporous smectic liquid crystal network (LCN) based on hydrogen bonded heterodimers is presented. The method relies on a supramolecular complex made from a pyridyl bearing reactive mesogen hydrogen bonded to a non-reactive benzoic acid template. Upon addition of a cross-linker, a smectic liquid crystalline phase is obtained that can be fixed by photopolymerization. It was found that the lamellar structure was maintained after template removal when 25 wt% or more cross-linker was used, yielding a nanoporous LCN. After H₃PO₄ immobilization in the pores of the LCN, a cationic 2D nanoporous polymer is obtained showing high and anisotropic anhydrous proton conductivity.

Originele taal-2	Engels
Pagina's (van-tot)	5018-5024
Aantal pagina's	7
Tijdschrift	Journal of Materials Chemistry C
Volume	6
Nummer van het tijdschrift	18
DOI's	https://doi.org/10.1039/c8tc00857d
Status	Gepubliceerd - 14 mei 2018

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Mulder, D. J., Liang, T., Xu, Y., ter Schiphorst, J., Scheres, L. M. W., Oosterlaken, B. M., ... Schenning, A. P. H. J. (2018). Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers. Journal of Materials Chemistry C, 6(18), 5018-5024. https://doi.org/10.1039/c8tc00857d

Mulder, Dirk Jan ; Liang, Ting ; Xu, Yifei ; ter Schiphorst, Jeroen ; Scheres, Luc M.W. ; Oosterlaken, Bernette M. ; Borneman, Zandrie ; Nijmeijer, Kitty ; Schenning, Albertus P.H.J. / Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers. In: Journal of Materials Chemistry C. 2018 ; Vol. 6, Nr. 18. blz. 5018-5024.

@article{aed603474672441da74ac1ae864a63ae,

title = "Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers",

abstract = "The fabrication of a cationic nanoporous smectic liquid crystal network (LCN) based on hydrogen bonded heterodimers is presented. The method relies on a supramolecular complex made from a pyridyl bearing reactive mesogen hydrogen bonded to a non-reactive benzoic acid template. Upon addition of a cross-linker, a smectic liquid crystalline phase is obtained that can be fixed by photopolymerization. It was found that the lamellar structure was maintained after template removal when 25 wt{\%} or more cross-linker was used, yielding a nanoporous LCN. After H3PO4 immobilization in the pores of the LCN, a cationic 2D nanoporous polymer is obtained showing high and anisotropic anhydrous proton conductivity.",

author = "Mulder, {Dirk Jan} and Ting Liang and Yifei Xu and {ter Schiphorst}, Jeroen and Scheres, {Luc M.W.} and Oosterlaken, {Bernette M.} and Zandrie Borneman and Kitty Nijmeijer and Schenning, {Albertus P.H.J.}",

year = "2018",

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doi = "10.1039/c8tc00857d",

language = "English",

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pages = "5018--5024",

journal = "Journal of Materials Chemistry C",

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Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers. / Mulder, Dirk Jan; Liang, Ting; Xu, Yifei; ter Schiphorst, Jeroen; Scheres, Luc M.W.; Oosterlaken, Bernette M.; Borneman, Zandrie ; Nijmeijer, Kitty ; Schenning, Albertus P.H.J.

In: Journal of Materials Chemistry C, Vol. 6, Nr. 18, 14.05.2018, blz. 5018-5024.

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

TY - JOUR

T1 - Proton conductive cationic nanoporous polymers based on smectic liquid crystal hydrogen-bonded heterodimers

AU - Mulder, Dirk Jan

AU - Liang, Ting

AU - Xu, Yifei

AU - ter Schiphorst, Jeroen

AU - Scheres, Luc M.W.

AU - Oosterlaken, Bernette M.

AU - Borneman, Zandrie

AU - Nijmeijer, Kitty

AU - Schenning, Albertus P.H.J.

PY - 2018/5/14

Y1 - 2018/5/14

N2 - The fabrication of a cationic nanoporous smectic liquid crystal network (LCN) based on hydrogen bonded heterodimers is presented. The method relies on a supramolecular complex made from a pyridyl bearing reactive mesogen hydrogen bonded to a non-reactive benzoic acid template. Upon addition of a cross-linker, a smectic liquid crystalline phase is obtained that can be fixed by photopolymerization. It was found that the lamellar structure was maintained after template removal when 25 wt% or more cross-linker was used, yielding a nanoporous LCN. After H3PO4 immobilization in the pores of the LCN, a cationic 2D nanoporous polymer is obtained showing high and anisotropic anhydrous proton conductivity.

AB - The fabrication of a cationic nanoporous smectic liquid crystal network (LCN) based on hydrogen bonded heterodimers is presented. The method relies on a supramolecular complex made from a pyridyl bearing reactive mesogen hydrogen bonded to a non-reactive benzoic acid template. Upon addition of a cross-linker, a smectic liquid crystalline phase is obtained that can be fixed by photopolymerization. It was found that the lamellar structure was maintained after template removal when 25 wt% or more cross-linker was used, yielding a nanoporous LCN. After H3PO4 immobilization in the pores of the LCN, a cationic 2D nanoporous polymer is obtained showing high and anisotropic anhydrous proton conductivity.

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U2 - 10.1039/c8tc00857d

DO - 10.1039/c8tc00857d

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