Process intensification in a microwave heated fine-chemical milli-plant at large scale operation

F. Benaskar, E. Rebrov, N.G. Patil, J. Meuldijk, L.A. Hulshof, V. Hessel, J.C. Schouten

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review

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Samenvatting

The integration of micro reactor technology and microwave heating has been investigated for two important classes of fine-chemical reactions, leading to improved catalyst surface and selective catalyst heating. A wall-coated micro reactor and a micro fixed-bed millireactor were designed and applied in the Ullmann-type C-O coupling of phenol and 4-chloropyridine and the Simmons-Smith cyclopropanation of styrene with ethyl diazoacetate. Volumetric microwave heating of the reactant fluids and local heating of CuZn/TiO2 catalyst could be established and resulted into an unprecedented continuous Cu-catalyzed liquid phase C-O coupling reaction with product yields up to 80%.
Originele taal-2Engels
TitelProceedings of the International Symposium on Chemical Reaction Engineering (ISCRE 22), 2-5 September 2012, Maastricht, the Nederlands
Plaats van productieMaastricht, the Nederlands
StatusGepubliceerd - 2012
Evenement22nd International Symposium on Chemical Reaction Engineering (ISCRE 22) - Maastricht, Nederland
Duur: 2 sep 20125 sep 2012

Congres

Congres22nd International Symposium on Chemical Reaction Engineering (ISCRE 22)
Verkorte titelISCRE 22
Land/RegioNederland
StadMaastricht
Periode2/09/125/09/12
Ander22nd International Symposium on Chemical Reaction and Engineering (ISCRE 2012), 2-5 September 2012

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