Photophysical properties of PPP and PPV derivatives bearing polystyrene or polycaprolactone as side groups

D.G. Colak; D.A.M. Egbe; E. Birckner; S. Yurteri; I. Cianga; E. Tekin; U.S. Schubert; Y. Yagci

doi:10.1016/j.eurpolymj.2008.11.040

Photophysical properties of PPP and PPV derivatives bearing polystyrene or polycaprolactone as side groups

D.G. Colak, D.A.M. Egbe, E. Birckner, S. Yurteri, I. Cianga, E. Tekin, U.S. Schubert, Y. Yagci

Chemical Engineering and Chemistry

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

8 Citaten (Scopus)

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The photophys. properties were studied of poly(p-phenylene) (PPP) and poly(p-phenylene-vinylene) (PPV) derivs. laterally decorated with polystyrene (PPV-PSt) or poly(e-caprolactone) (PPP-PCL, PPP- alt PCL, PPV-PCL and PPV-PCL-Br). The polymers emit blue light and exhibit high relative and abs. photoluminescence quantum yield (Ff), in dil. soln., thin film (spin-coated and inkjet-printed), and bulk state. These parameters are ascribed to the side groups, which suppress the strong pi-pi interactions and, consequently, excimer formation. Lower Ff was obsd. for PPV-PCL-Br and its corresponding model compd. dibromo-distyrylbenzene Br2-DSB, which was ascribed to heavy atom effect enabling intersystem crossing from S1 to T1. However, studies at 77 K did not reveal phosphorescence; in contrast, an enhancement of the fluorescence intensity with respect to room temp. measurements was obsd.

Originele taal-2	Engels
Pagina's (van-tot)	940-945
Tijdschrift	European Polymer Journal
Volume	45
Nummer van het tijdschrift	3
DOI's	https://doi.org/10.1016/j.eurpolymj.2008.11.040
Status	Gepubliceerd - 2009

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10.1016/j.eurpolymj.2008.11.040

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@article{9ae2f402cbb84a249b8c4d3d33a2f13b,

title = "Photophysical properties of PPP and PPV derivatives bearing polystyrene or polycaprolactone as side groups",

abstract = "The photophys. properties were studied of poly(p-phenylene) (PPP) and poly(p-phenylene-vinylene) (PPV) derivs. laterally decorated with polystyrene (PPV-PSt) or poly(e-caprolactone) (PPP-PCL, PPP- alt PCL, PPV-PCL and PPV-PCL-Br). The polymers emit blue light and exhibit high relative and abs. photoluminescence quantum yield (Ff), in dil. soln., thin film (spin-coated and inkjet-printed), and bulk state. These parameters are ascribed to the side groups, which suppress the strong pi-pi interactions and, consequently, excimer formation. Lower Ff was obsd. for PPV-PCL-Br and its corresponding model compd. dibromo-distyrylbenzene Br2-DSB, which was ascribed to heavy atom effect enabling intersystem crossing from S1 to T1. However, studies at 77 K did not reveal phosphorescence; in contrast, an enhancement of the fluorescence intensity with respect to room temp. measurements was obsd.",

author = "D.G. Colak and D.A.M. Egbe and E. Birckner and S. Yurteri and I. Cianga and E. Tekin and U.S. Schubert and Y. Yagci",

year = "2009",

doi = "10.1016/j.eurpolymj.2008.11.040",

language = "English",

volume = "45",

pages = "940--945",

journal = "European Polymer Journal",

issn = "0014-3057",

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TY - JOUR

T1 - Photophysical properties of PPP and PPV derivatives bearing polystyrene or polycaprolactone as side groups

AU - Colak, D.G.

AU - Egbe, D.A.M.

AU - Birckner, E.

AU - Yurteri, S.

AU - Cianga, I.

AU - Tekin, E.

AU - Schubert, U.S.

AU - Yagci, Y.

PY - 2009

Y1 - 2009

N2 - The photophys. properties were studied of poly(p-phenylene) (PPP) and poly(p-phenylene-vinylene) (PPV) derivs. laterally decorated with polystyrene (PPV-PSt) or poly(e-caprolactone) (PPP-PCL, PPP- alt PCL, PPV-PCL and PPV-PCL-Br). The polymers emit blue light and exhibit high relative and abs. photoluminescence quantum yield (Ff), in dil. soln., thin film (spin-coated and inkjet-printed), and bulk state. These parameters are ascribed to the side groups, which suppress the strong pi-pi interactions and, consequently, excimer formation. Lower Ff was obsd. for PPV-PCL-Br and its corresponding model compd. dibromo-distyrylbenzene Br2-DSB, which was ascribed to heavy atom effect enabling intersystem crossing from S1 to T1. However, studies at 77 K did not reveal phosphorescence; in contrast, an enhancement of the fluorescence intensity with respect to room temp. measurements was obsd.

AB - The photophys. properties were studied of poly(p-phenylene) (PPP) and poly(p-phenylene-vinylene) (PPV) derivs. laterally decorated with polystyrene (PPV-PSt) or poly(e-caprolactone) (PPP-PCL, PPP- alt PCL, PPV-PCL and PPV-PCL-Br). The polymers emit blue light and exhibit high relative and abs. photoluminescence quantum yield (Ff), in dil. soln., thin film (spin-coated and inkjet-printed), and bulk state. These parameters are ascribed to the side groups, which suppress the strong pi-pi interactions and, consequently, excimer formation. Lower Ff was obsd. for PPV-PCL-Br and its corresponding model compd. dibromo-distyrylbenzene Br2-DSB, which was ascribed to heavy atom effect enabling intersystem crossing from S1 to T1. However, studies at 77 K did not reveal phosphorescence; in contrast, an enhancement of the fluorescence intensity with respect to room temp. measurements was obsd.

U2 - 10.1016/j.eurpolymj.2008.11.040

DO - 10.1016/j.eurpolymj.2008.11.040

M3 - Article

SN - 0014-3057

VL - 45

SP - 940

EP - 945

JO - European Polymer Journal

JF - European Polymer Journal

IS - 3

ER -

Photophysical properties of PPP and PPV derivatives bearing polystyrene or polycaprolactone as side groups

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