Photocatalytic activity of exfoliated graphite-TiO2 nanoparticle composites

Gloria Guidetti, Eva A.A. Pogna, Lucia Lombardi, Flavia Tomarchio, Iryna Polishchuk, Rick R.M. Joosten, Alessandro Ianiro, Giancarlo Soavi, Nico A.J.M. Sommerdijk, Heiner Friedrich, Boaz Pokroy, Anna K. Ott, Marco Goisis, Francesco Zerbetto, Giuseppe Falini, Matteo Calvaresi, Andrea C. Ferrari, Giulio Cerullo, Marco Montalti (Corresponding author)

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Samenvatting

We investigate the photocatalytic performance of composites prepared in a one-step process by liquid-phase exfoliation of graphite in the presence of TiO2 nanoparticles (NPs) at atmospheric pressure and in water, without heating or adding any surfactant, and starting from low-cost commercial reagents. These show enhanced photocatalytic activity, degrading up to 40% more pollutants with respect to the starting TiO2-NPs, in the case of a model dye target, and up to 70% more pollutants in the case of nitrogen oxides. In order to understand the photo-physical mechanisms underlying this enhancement, we investigate the photo-generation of reactive species (trapped holes and electrons) by ultrafast transient absorption spectroscopy. We observe an electron transfer process from TiO2 to the graphite flakes within the first picoseconds of the relaxation dynamics, which causes the decrease of the charge recombination rate, and increases the efficiency of the reactive species photo-production.

Originele taal-2Engels
Pagina's (van-tot)19301-19314
Aantal pagina's14
TijdschriftNanoscale
Volume11
Nummer van het tijdschrift41
DOI's
StatusGepubliceerd - 7 nov 2019

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    Guidetti, G., Pogna, E. A. A., Lombardi, L., Tomarchio, F., Polishchuk, I., Joosten, R. R. M., Ianiro, A., Soavi, G., Sommerdijk, N. A. J. M., Friedrich, H., Pokroy, B., Ott, A. K., Goisis, M., Zerbetto, F., Falini, G., Calvaresi, M., Ferrari, A. C., Cerullo, G., & Montalti, M. (2019). Photocatalytic activity of exfoliated graphite-TiO2 nanoparticle composites. Nanoscale, 11(41), 19301-19314. https://doi.org/10.1039/c9nr06760d