Samenvatting
MIL-101, a chromium-based metal–organic framework, is known for its very large pore size, large surface area and good stability. However, applications of this material in catalysis are still limited. 5-Hydroxymethylfurfural (HMF) has been considered a renewable chemical platform for the production of liquid fuels and fine chemicals. Phosphotungstic acid, H3PW12O40 (PTA), encapsulated in MIL-101 is evaluated as a potential catalyst for the selective dehydration of fructose and glucose to 5-hydroxymethylfurfural. The results demonstrate that PTA/MIL-101 is effective for HMF production from fructose in DMSO and can be reused. This is the first example of the application of a metal–organic framework in carbohydrate dehydration.
| Originele taal-2 | Engels |
|---|---|
| Pagina's (van-tot) | 59-64 |
| Aantal pagina's | 6 |
| Tijdschrift | ChemSusChem |
| Volume | 4 |
| Nummer van het tijdschrift | 1 |
| DOI's | |
| Status | Gepubliceerd - 2011 |
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