On the role of C2O radicals in the prompt-NO mechanism

A.A. Konnov

    Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

    4 Citaten (Scopus)

    Samenvatting

    The measurements of NO concentrations in the post-flame zone of different hydrocarbon + O2 + N2 flames at standard temperature and atmospheric pressure available in the literature are compared with predictions of the original Konnov reaction mechanism and with the same mechanism extended by the reaction of C2O with N2. The goal was to investigate the possible role of this reaction proposed by Williams and Fleming [Proc. Combust. Inst., Vol. 31 (2007), pp. 1109–1117]. This new reaction of C2O with N2 seems to be a reasonable explanation of the deficiencies in the prompt-NO route. Direct comparisons of the experimental measurements performed in different flames with the modeling strongly suggests that the upper limit of this reaction rate constant is k = 7 · 10^11 exp(-17,000/RT) [cm3/(mole · sec)].
    Originele taal-2Engels
    Pagina's (van-tot)497-501
    TijdschriftCombustion, Explosion and Shock Waves
    Volume44
    Nummer van het tijdschrift5
    DOI's
    StatusGepubliceerd - 2008

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