Nitrate reduction on Pt(1 1 1) surfaces modified by Bi adatoms

Marta C. Figueiredo, Janaína Souza-Garcia, Victor Climent, Juan M. Feliu (Corresponding author)

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

24 Citaten (Scopus)

Samenvatting

This work presents the effect of Bi modification of Pt(1 1 1) electrodes on the electroreduction of nitrate anions by using voltammetric and FTIR experiments. On Pt(1 1 1) nitrate consumption occurs at potentials lower than 0.35 V, but with Pt(1 1 1)/Bi this process is shifted to significantly higher potentials (0.6-0.7 V). In the latter surface N2O was observed as the main product in solution. Different forms of adsorbed NO were detected on the adatom covered surfaces as well as on clean Pt(1 1 1).

Originele taal-2Engels
Pagina's (van-tot)1760-1763
Aantal pagina's4
TijdschriftElectrochemistry Communications
Volume11
Nummer van het tijdschrift9
DOI's
StatusGepubliceerd - 1 sep 2009
Extern gepubliceerdJa

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