New Ti-Ni dense membranes with low palladium content

G.F. Tereschenko, M.M. Ermilova, V.P. Mordovin, N.V. Orekhova, V.M. Gryaznov, A. Iulianelli, F. Gallucci, A. Basile

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

31 Citaten (Scopus)

Samenvatting

The method of preparation of thin foil Ti-Ni-Pd alloy membranes with 2, 5 and 9 wt% of Pd was developed and the phase content and hydrogen permeability of membranes were studied. It was found that Pd adding into Ti-Ni alloy increases the hydrogen permeability of the foils. Thus, the permeability of the foil with 9% of Pd was about one order of magnitude higher than that of the Ti-Ni foil. Cyclohexane dehydrogenation on Pt - Re / Al2 O3 commercial catalyst carried out in a flow reactor with a Ti-Ni-Pd membrane shows the higher conversions than those of a reactor without membrane due to the hydrogen permeability through the membrane. © 2007 International Association for Hydrogen Energy. 10.1016/j.ijhydene.2007.03.044
Originele taal-2Engels
Pagina's (van-tot)4016-4022
Aantal pagina's7
TijdschriftInternational Journal of Hydrogen Energy
Volume32
Nummer van het tijdschrift16
DOI's
StatusGepubliceerd - 2007

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