Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

C.L. Gonzalez; C.W.M. Bastiaansen; Johan Lub; J. Loos; K. Lu; H.J. Wondergem; D.J. Broer

doi:10.1002/adma.200702002

Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

C.L. Gonzalez, C.W.M. Bastiaansen, Johan Lub, J. Loos, K. Lu, H.J. Wondergem, D.J. Broer

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.

Originele taal-2	Engels
Pagina's (van-tot)	1246-1252
Aantal pagina's	7
Tijdschrift	Advanced Materials
Volume	20
Nummer van het tijdschrift	7
DOI's	https://doi.org/10.1002/adma.200702002
Status	Gepubliceerd - 2008

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10.1002/adma.200702002

Center for Multiscale Electron Microscopy (CMEM)
Heiner Friedrich (Manager), Rick Joosten (Education/onderzoek medewerker), Pauline Schmit (Education/onderzoek medewerker), Ingeborg Schreur - Piet (Inhoud) & Anne Spoelstra (Education/onderzoek medewerker)
Physical Chemistry
Uitrusting/faciliteit: Onderzoekslaboratorium

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abstract = "Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.",

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AU - Lu, K.

AU - Wondergem, H.J.

AU - Broer, D.J.

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AB - Nanoporous membranes are made based on photoreactive hydrogen-bridged smectic liquid crystal dimers. The self-assembled layered structure is locked by photopolymerization. The hydrogen bridges are reversibly opened by heating or by changing the pH. This forms periodic pores of which the integrity is conserved by a covalent crosslinker, setting the spacing at ca. 1 nm. The pores are covered with carboxylic anions that bind to cations or to amines.

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Nanoporous membranes of hydrogen-bridged smectic networks with nanometer transverse pore dimensions

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Center for Multiscale Electron Microscopy (CMEM)

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