Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions

M.A. Tas, R.M. van Hardeveld, E.M. Veldhuizen, van, R.A. Santen, van

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review

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Uittreksel

A model is developed to describe the transfer of vibrational energy from excited gas molecules to a heterogeneous surface or to heating of the gas. Diffusion of excited species is included in the model. The model is used to compute the maximum possible energy efficiency of a plasma-induced catalytic reaction, which is driven by vibrationally excited molecules. The computational results of the model are correlated to experimental data on quenching rates and the relevant parameters of the self-sustained discharge. It is con cluded that the mechanism of plasma-induced catalysis with vibrationally excited molecules is highly unlikely.
Originele taal-2Engels
TitelProceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA
RedacteurenJ.V. Heberlein, D.W. Ernie, J.T. Roberts
Plaats van productieMinneapolis, Minn.
UitgeverijAmerican Physical Society
Pagina's481-486
ISBN van geprinte versie1-88797-600-0
StatusGepubliceerd - 1995
Evenement12th International Symposium on Plasma Chemistry (ISPC 12), August 21-25, 1995, Minneapolis, MN, USA - Minneapolis, MN, Verenigde Staten van Amerika
Duur: 21 aug 199525 aug 1995

Congres

Congres12th International Symposium on Plasma Chemistry (ISPC 12), August 21-25, 1995, Minneapolis, MN, USA
Verkorte titelISPC 12
LandVerenigde Staten van Amerika
StadMinneapolis, MN
Periode21/08/9525/08/95
AnderProc. 12th International Symposium on Plasma Chemistry (ISPC)

Vingerafdruk

Plasmas
Molecules
Gases
Catalysis
Energy efficiency
Quenching
Heating

Citeer dit

Tas, M. A., van Hardeveld, R. M., Veldhuizen, van, E. M., & Santen, van, R. A. (1995). Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions. In J. V. Heberlein, D. W. Ernie, & J. T. Roberts (editors), Proceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA (blz. 481-486). Minneapolis, Minn.: American Physical Society.
Tas, M.A. ; van Hardeveld, R.M. ; Veldhuizen, van, E.M. ; Santen, van, R.A. / Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions. Proceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA. redacteur / J.V. Heberlein ; D.W. Ernie ; J.T. Roberts. Minneapolis, Minn. : American Physical Society, 1995. blz. 481-486
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abstract = "A model is developed to describe the transfer of vibrational energy from excited gas molecules to a heterogeneous surface or to heating of the gas. Diffusion of excited species is included in the model. The model is used to compute the maximum possible energy efficiency of a plasma-induced catalytic reaction, which is driven by vibrationally excited molecules. The computational results of the model are correlated to experimental data on quenching rates and the relevant parameters of the self-sustained discharge. It is con cluded that the mechanism of plasma-induced catalysis with vibrationally excited molecules is highly unlikely.",
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Tas, MA, van Hardeveld, RM, Veldhuizen, van, EM & Santen, van, RA 1995, Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions. in JV Heberlein, DW Ernie & JT Roberts (redactie), Proceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA. American Physical Society, Minneapolis, Minn., blz. 481-486, 12th International Symposium on Plasma Chemistry (ISPC 12), August 21-25, 1995, Minneapolis, MN, USA, Minneapolis, MN, Verenigde Staten van Amerika, 21/08/95.

Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions. / Tas, M.A.; van Hardeveld, R.M.; Veldhuizen, van, E.M.; Santen, van, R.A.

Proceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA. redactie / J.V. Heberlein; D.W. Ernie; J.T. Roberts. Minneapolis, Minn. : American Physical Society, 1995. blz. 481-486.

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review

TY - GEN

T1 - Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions

AU - Tas, M.A.

AU - van Hardeveld, R.M.

AU - Veldhuizen, van, E.M.

AU - Santen, van, R.A.

PY - 1995

Y1 - 1995

N2 - A model is developed to describe the transfer of vibrational energy from excited gas molecules to a heterogeneous surface or to heating of the gas. Diffusion of excited species is included in the model. The model is used to compute the maximum possible energy efficiency of a plasma-induced catalytic reaction, which is driven by vibrationally excited molecules. The computational results of the model are correlated to experimental data on quenching rates and the relevant parameters of the self-sustained discharge. It is con cluded that the mechanism of plasma-induced catalysis with vibrationally excited molecules is highly unlikely.

AB - A model is developed to describe the transfer of vibrational energy from excited gas molecules to a heterogeneous surface or to heating of the gas. Diffusion of excited species is included in the model. The model is used to compute the maximum possible energy efficiency of a plasma-induced catalytic reaction, which is driven by vibrationally excited molecules. The computational results of the model are correlated to experimental data on quenching rates and the relevant parameters of the self-sustained discharge. It is con cluded that the mechanism of plasma-induced catalysis with vibrationally excited molecules is highly unlikely.

M3 - Conference contribution

SN - 1-88797-600-0

SP - 481

EP - 486

BT - Proceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA

A2 - Heberlein, J.V.

A2 - Ernie, D.W.

A2 - Roberts, J.T.

PB - American Physical Society

CY - Minneapolis, Minn.

ER -

Tas MA, van Hardeveld RM, Veldhuizen, van EM, Santen, van RA. Modeling of the reactivity of vibrationally excited molecules in a corona plasma for catalytic reactions. In Heberlein JV, Ernie DW, Roberts JT, redacteurs, Proceedings of the 12th International Symposium on Plasma Chemistry (ISPC-12) 21-25 August 1995 Minneapolis, Minnesota, USA. Minneapolis, Minn.: American Physical Society. 1995. blz. 481-486