Mesophase-mediated crystallization of poly(butylene-2,6-naphthalate): an example of Ostwald's rule of stages

D. Cavallo; D. Mileva; G. Portale; L. Zhang; L. Balzano; G.C. Alfonso; R. Androsch

doi:10.1021/mz300349z

Mesophase-mediated crystallization of poly(butylene-2,6-naphthalate): an example of Ostwald's rule of stages

D. Cavallo, D. Mileva, G. Portale, L. Zhang, L. Balzano, G.C. Alfonso, R. Androsch

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

46 Citaties (SciVal)

Samenvatting

The investigation of poly(butylene-2,6-naphthalate) crystallization by means of chip-calorimetry and ultrafast wide-angle X-ray diffraction (WAXD) revealed the existence of two possible mechanisms. The formation Of the stable triclinic-alpha-phase occurs directly from the undercooled melt at law cooling rates/high crystallization temperature. At higher cooling rates a two-stage route is observed: crystallization is preceded by the formation of a mesomorphic phase from the isotropic melt The monotiopic behavior of poly(butylene-2,6-naphthalate), becoming apparent only under severe cooling conditions, obeys the well-known Ostwald's rule of stages

Originele taal-2	Engels
Pagina's (van-tot)	1051-1055
Tijdschrift	ACS Macro Letters
Volume	1
Nummer van het tijdschrift	8
DOI's	https://doi.org/10.1021/mz300349z
Status	Gepubliceerd - 2012

Toegang tot document

10.1021/mz300349z

Citeer dit

@article{0b60d105d2e34a0095e727f8e26e03ae,

title = "Mesophase-mediated crystallization of poly(butylene-2,6-naphthalate): an example of Ostwald's rule of stages",

abstract = "The investigation of poly(butylene-2,6-naphthalate) crystallization by means of chip-calorimetry and ultrafast wide-angle X-ray diffraction (WAXD) revealed the existence of two possible mechanisms. The formation Of the stable triclinic-alpha-phase occurs directly from the undercooled melt at law cooling rates/high crystallization temperature. At higher cooling rates a two-stage route is observed: crystallization is preceded by the formation of a mesomorphic phase from the isotropic melt The monotiopic behavior of poly(butylene-2,6-naphthalate), becoming apparent only under severe cooling conditions, obeys the well-known Ostwald's rule of stages",

author = "D. Cavallo and D. Mileva and G. Portale and L. Zhang and L. Balzano and G.C. Alfonso and R. Androsch",

year = "2012",

doi = "10.1021/mz300349z",

language = "English",

volume = "1",

pages = "1051--1055",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - Mesophase-mediated crystallization of poly(butylene-2,6-naphthalate): an example of Ostwald's rule of stages

AU - Cavallo, D.

AU - Mileva, D.

AU - Portale, G.

AU - Zhang, L.

AU - Balzano, L.

AU - Alfonso, G.C.

AU - Androsch, R.

PY - 2012

Y1 - 2012

N2 - The investigation of poly(butylene-2,6-naphthalate) crystallization by means of chip-calorimetry and ultrafast wide-angle X-ray diffraction (WAXD) revealed the existence of two possible mechanisms. The formation Of the stable triclinic-alpha-phase occurs directly from the undercooled melt at law cooling rates/high crystallization temperature. At higher cooling rates a two-stage route is observed: crystallization is preceded by the formation of a mesomorphic phase from the isotropic melt The monotiopic behavior of poly(butylene-2,6-naphthalate), becoming apparent only under severe cooling conditions, obeys the well-known Ostwald's rule of stages

AB - The investigation of poly(butylene-2,6-naphthalate) crystallization by means of chip-calorimetry and ultrafast wide-angle X-ray diffraction (WAXD) revealed the existence of two possible mechanisms. The formation Of the stable triclinic-alpha-phase occurs directly from the undercooled melt at law cooling rates/high crystallization temperature. At higher cooling rates a two-stage route is observed: crystallization is preceded by the formation of a mesomorphic phase from the isotropic melt The monotiopic behavior of poly(butylene-2,6-naphthalate), becoming apparent only under severe cooling conditions, obeys the well-known Ostwald's rule of stages

U2 - 10.1021/mz300349z

DO - 10.1021/mz300349z

M3 - Article

SN - 2161-1653

VL - 1

SP - 1051

EP - 1055

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 8

ER -

Mesophase-mediated crystallization of poly(butylene-2,6-naphthalate): an example of Ostwald's rule of stages

Samenvatting

Toegang tot document

Vingerafdruk

Citeer dit