Kinetic protium-deuterium isotope effect in an intramolecular 1-5 shift of hydrogen

H. Kloosterziel; A.P. Borg, ter

doi:10.1002/recl.19650841012

Kinetic protium-deuterium isotope effect in an intramolecular 1-5 shift of hydrogen

H. Kloosterziel
, A.P. Borg, ter

Chemical Engineering and Chemistry

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

24 Citaten (Scopus)

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The thermal isomerization of 5,8-dideuterocycloocta-1,3,6-triene to the 1,3,5-isomer has been studied. From the rate, as compared with that of the unlabelled compound, and from the distribution of the label in the rearranged material, values were obtained for the primary and secondary kinetic isotope effects. The large value of 5.0 at 120° for the former tallies with a nearly symmetrical transition state.

Originele taal-2	Engels
Pagina's (van-tot)	1305-1314
Tijdschrift	Recueil des Travaux Chimiques des Pays-Bas
Volume	84
Nummer van het tijdschrift	10
DOI's	https://doi.org/10.1002/recl.19650841012
Status	Gepubliceerd - 1965

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10.1002/recl.19650841012

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title = "Kinetic protium-deuterium isotope effect in an intramolecular 1-5 shift of hydrogen",

abstract = "The thermal isomerization of 5,8-dideuterocycloocta-1,3,6-triene to the 1,3,5-isomer has been studied. From the rate, as compared with that of the unlabelled compound, and from the distribution of the label in the rearranged material, values were obtained for the primary and secondary kinetic isotope effects. The large value of 5.0 at 120° for the former tallies with a nearly symmetrical transition state.",

author = "H. Kloosterziel and \{Borg, ter\}, A.P.",

year = "1965",

doi = "10.1002/recl.19650841012",

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issn = "0165-0513",

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TY - JOUR

T1 - Kinetic protium-deuterium isotope effect in an intramolecular 1-5 shift of hydrogen

AU - Kloosterziel, H.

AU - Borg, ter, A.P.

PY - 1965

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N2 - The thermal isomerization of 5,8-dideuterocycloocta-1,3,6-triene to the 1,3,5-isomer has been studied. From the rate, as compared with that of the unlabelled compound, and from the distribution of the label in the rearranged material, values were obtained for the primary and secondary kinetic isotope effects. The large value of 5.0 at 120° for the former tallies with a nearly symmetrical transition state.

AB - The thermal isomerization of 5,8-dideuterocycloocta-1,3,6-triene to the 1,3,5-isomer has been studied. From the rate, as compared with that of the unlabelled compound, and from the distribution of the label in the rearranged material, values were obtained for the primary and secondary kinetic isotope effects. The large value of 5.0 at 120° for the former tallies with a nearly symmetrical transition state.

U2 - 10.1002/recl.19650841012

DO - 10.1002/recl.19650841012

M3 - Article

SN - 0165-0513

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SP - 1305

EP - 1314

JO - Recueil des Travaux Chimiques des Pays-Bas

JF - Recueil des Travaux Chimiques des Pays-Bas

IS - 10

ER -

Kinetic protium-deuterium isotope effect in an intramolecular 1-5 shift of hydrogen

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