Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

M. Geus, de; J.W. Peeters; M. Wolffs; T.M. Hermans; A.R.A. Palmans; C.E. Koning; A. Heise

doi:10.1021/ma0473871

Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

M. Geus, de, J.W. Peeters, M. Wolffs, T.M. Hermans, A.R.A. Palmans, C.E. Koning, A. Heise

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

66 Citaten (Scopus)

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The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to

Originele taal-2	Engels
Pagina's (van-tot)	4220-4225
Tijdschrift	Macromolecules
Volume	38
Nummer van het tijdschrift	10
DOI's	https://doi.org/10.1021/ma0473871
Status	Gepubliceerd - 2005

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10.1021/ma0473871

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abstract = "The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to",

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T1 - Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

AU - Geus, de, M.

AU - Peeters, J.W.

AU - Wolffs, M.

AU - Hermans, T.M.

AU - Palmans, A.R.A.

AU - Koning, C.E.

AU - Heise, A.

PY - 2005

Y1 - 2005

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AB - The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to

U2 - 10.1021/ma0473871

DO - 10.1021/ma0473871

M3 - Article

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VL - 38

SP - 4220

EP - 4225

JO - Macromolecules

JF - Macromolecules

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Investigation of factors influencing the chemoenzymatic synthesis of block copolymers

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