Intramolecular hydrogen bonding in acylated 2,2'bipyridine-3,3'-diamines

A.R.A. Palmans, J.A.J.M. Vekemans, E.W. Meijer

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Various di- and monoacylated 2,2'-bipyridine-3,3'-diamines (amides 1a-f, 8, 9, ureas 1g-h, 8b and acylureas 1i-j) have been synthesized and characterized. All molecules show strong intramolecular hydrogen bonding between the acyl NH of one ring and the pyridine N-1 of the other (and vice versa), as is deduced from the low field 1H NMR resonances of the acyl NH protons, which range from d 12.6 to 15.0 ppm in CDCl3. The nature of the secondary structure of the (di)acylated 2,2'-bipyridine-3,3'-diamines has been investigated using a variety of techniques including variable-temperature 1H NMR and CD spectroscopy.
Originele taal-2Engels
Pagina's (van-tot)277-284
Aantal pagina's8
TijdschriftRecueil des Travaux Chimiques des Pays-Bas
Nummer van het tijdschrift6
StatusGepubliceerd - 1995


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