Imaging of n-hexane in zeolites by positron emission profiling (PEP)

R.A. van Santen, B.G. Anderson, R.H. Cunningham, A.V.G. Mangnus, J. van Grondelle, L.J. IJzendoorn, van

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademic

5 Citaties (Scopus)
55 Downloads (Pure)

Uittreksel

Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse
Originele taal-2Engels
Titel11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B
RedacteurenJ.W. Hightower, W.N. Delgass, E. Iglesia, A.T. Bell
Plaats van productieAmsterdam
UitgeverijElsevier
Pagina's791-800
ISBN van geprinte versie0-444-81947-9
DOI's
StatusGepubliceerd - 1996
Evenement11th International Congress on Catalysis (ICC 1996) - Baltimore, MD, Verenigde Staten van Amerika
Duur: 30 jun 19965 jul 1996
Congresnummer: 11

Publicatie series

NaamStudies in Surface Science and Catalysis
NummerPart B
Volume101
ISSN van geprinte versie0167-2991

Congres

Congres11th International Congress on Catalysis (ICC 1996)
Verkorte titelICC 1996
LandVerenigde Staten van Amerika
StadBaltimore, MD
Periode30/06/965/07/96

Vingerafdruk

zeolites
positrons
pulses
in situ measurement
alkenes
tracers
cyclotrons
partial pressure
molecules
temperature

Citeer dit

van Santen, R. A., Anderson, B. G., Cunningham, R. H., Mangnus, A. V. G., van Grondelle, J., & IJzendoorn, van, L. J. (1996). Imaging of n-hexane in zeolites by positron emission profiling (PEP). In J. W. Hightower, W. N. Delgass, E. Iglesia, & A. T. Bell (editors), 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B (blz. 791-800). (Studies in Surface Science and Catalysis; Vol. 101, Nr. Part B). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(96)80290-4
van Santen, R.A. ; Anderson, B.G. ; Cunningham, R.H. ; Mangnus, A.V.G. ; van Grondelle, J. ; IJzendoorn, van, L.J. / Imaging of n-hexane in zeolites by positron emission profiling (PEP). 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. redacteur / J.W. Hightower ; W.N. Delgass ; E. Iglesia ; A.T. Bell. Amsterdam : Elsevier, 1996. blz. 791-800 (Studies in Surface Science and Catalysis; Part B).
@inproceedings{06130f40f9854d5d9198de99101a98af,
title = "Imaging of n-hexane in zeolites by positron emission profiling (PEP)",
abstract = "Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse",
author = "{van Santen}, R.A. and B.G. Anderson and R.H. Cunningham and A.V.G. Mangnus and {van Grondelle}, J. and {IJzendoorn, van}, L.J.",
year = "1996",
doi = "10.1016/S0167-2991(96)80290-4",
language = "English",
isbn = "0-444-81947-9",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier",
number = "Part B",
pages = "791--800",
editor = "J.W. Hightower and W.N. Delgass and E. Iglesia and A.T. Bell",
booktitle = "11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B",
address = "Netherlands",

}

van Santen, RA, Anderson, BG, Cunningham, RH, Mangnus, AVG, van Grondelle, J & IJzendoorn, van, LJ 1996, Imaging of n-hexane in zeolites by positron emission profiling (PEP). in JW Hightower, WN Delgass, E Iglesia & AT Bell (redactie), 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. Studies in Surface Science and Catalysis, nr. Part B, vol. 101, Elsevier, Amsterdam, blz. 791-800, 11th International Congress on Catalysis (ICC 1996), Baltimore, MD, Verenigde Staten van Amerika, 30/06/96. https://doi.org/10.1016/S0167-2991(96)80290-4

Imaging of n-hexane in zeolites by positron emission profiling (PEP). / van Santen, R.A.; Anderson, B.G.; Cunningham, R.H.; Mangnus, A.V.G.; van Grondelle, J.; IJzendoorn, van, L.J.

11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. redactie / J.W. Hightower; W.N. Delgass; E. Iglesia; A.T. Bell. Amsterdam : Elsevier, 1996. blz. 791-800 (Studies in Surface Science and Catalysis; Vol. 101, Nr. Part B).

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademic

TY - GEN

T1 - Imaging of n-hexane in zeolites by positron emission profiling (PEP)

AU - van Santen, R.A.

AU - Anderson, B.G.

AU - Cunningham, R.H.

AU - Mangnus, A.V.G.

AU - van Grondelle, J.

AU - IJzendoorn, van, L.J.

PY - 1996

Y1 - 1996

N2 - Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse

AB - Positron Emission Profiling (PEP) has been used for in-situ measurement of the surface coverage of H-mordenite by n-hexane, as a function of hexane partial pressure, at the elevated temperatures typically used for hydroisomerization by monitoring the retention time of an injected radio-labelled pulse of n-hexane. The labelled molecules ((CH3C5H11)-C-11) were produced via a two-step alkene homologation reaction in which C-11, produced using a cyclotron, was added to 1-pentene. The PEP method described is similar to the ''tracer pulse technique'' however it has the significant advantage of in-situ imaging of the pulse

U2 - 10.1016/S0167-2991(96)80290-4

DO - 10.1016/S0167-2991(96)80290-4

M3 - Conference contribution

SN - 0-444-81947-9

T3 - Studies in Surface Science and Catalysis

SP - 791

EP - 800

BT - 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B

A2 - Hightower, J.W.

A2 - Delgass, W.N.

A2 - Iglesia, E.

A2 - Bell, A.T.

PB - Elsevier

CY - Amsterdam

ER -

van Santen RA, Anderson BG, Cunningham RH, Mangnus AVG, van Grondelle J, IJzendoorn, van LJ. Imaging of n-hexane in zeolites by positron emission profiling (PEP). In Hightower JW, Delgass WN, Iglesia E, Bell AT, redacteurs, 11th international congress on catalysis-40th anniversary; proceedings of the11th ICC, Baltimore, MD, USA 30-06-1996 - 5-07-1996. Part B. Amsterdam: Elsevier. 1996. blz. 791-800. (Studies in Surface Science and Catalysis; Part B). https://doi.org/10.1016/S0167-2991(96)80290-4