Hydrogen storage in sonicated carbon materials

M. Hirscher, M. Becher, M. Haluska, U. Dettlaff-Weglikowska, A. Quintel, G.S. Duesberg, Y.J. Choi, P. Downes, M. Hulman, S. Roth, I. Stepanek, P. Bernier

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

299 Citaten (Scopus)

Samenvatting

The hydrogen storage in purified single-wall carbon nanotubes (SWNTs), graphite and diamond powder was investigated at room temperature and ambient pressure. The samples were sonicated in 5 M HNO3 for various periods of time using an ultrasonic probe of the alloy Ti-6Al-4V. The goal of this treatment was to open the carbon nanotubes. The maximum value of overall hydrogen storage was found to be 1.5 wt¿%, as determined by thermal desorption spectroscopy. The storage capacity increases with sonication time. The sonication treatment introduces particles of the Ti alloy into the samples, as shown by X-ray diffraction, transmission electron microscopy, and chemical analysis. All of the hydrogen uptake can be explained by the assumption that the hydrogen is only stored in the Ti-alloy particles. The presence of Ti-alloy particles does not allow the determination of whether a small amount of hydrogen possibly is stored in the SWNTs themselves, and the fraction of nanotubes opened by the sonication treatment is unknown.
Originele taal-2Engels
Pagina's (van-tot)129-132
TijdschriftApplied Physics A: Materials Science & Processing
Volume72
Nummer van het tijdschrift2
DOI's
StatusGepubliceerd - 2001

Vingerafdruk

Duik in de onderzoeksthema's van 'Hydrogen storage in sonicated carbon materials'. Samen vormen ze een unieke vingerafdruk.

Citeer dit