Homologation reactions of alkanes on transition-metal surfaces

R.H. Cunningham, R.A. Santen, van, A.V.G. Mangnus, J.H.B.J. Hoebink

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review

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Samenvatting

A symposia; a combination of expts. using TAP, and isotopic labeling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temp. CO or CH4 adsorption was shown to be more likely at high temps., and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso-ratio between labeled and non-labeled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane
Originele taal-2Engels
TitelMethane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994
RedacteurenD.W. Slocum
Plaats van productieNew York
UitgeverijPlenum Press
Pagina's59-69
ISBN van geprinte versie0-306-45212-X
StatusGepubliceerd - 1995
Evenementconference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17 -
Duur: 13 mrt 199417 mrt 1994

Congres

Congresconference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17
Periode13/03/9417/03/94
AnderAmerican Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17

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  • Citeer dit

    Cunningham, R. H., Santen, van, R. A., Mangnus, A. V. G., & Hoebink, J. H. B. J. (1995). Homologation reactions of alkanes on transition-metal surfaces. In D. W. Slocum (editor), Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994 (blz. 59-69). New York: Plenum Press.