Homologation reactions of alkanes on transition-metal surfaces

R.H. Cunningham; R.A. Santen, van; A.V.G. Mangnus; J.H.B.J. Hoebink

Homologation reactions of alkanes on transition-metal surfaces

R.H. Cunningham, R.A. Santen, van, A.V.G. Mangnus, J.H.B.J. Hoebink

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/Congresprocedure › Conferentiebijdrage › Academic › peer review

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A symposia; a combination of expts. using TAP, and isotopic labeling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temp. CO or CH4 adsorption was shown to be more likely at high temps., and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso-ratio between labeled and non-labeled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane

Originele taal-2	Engels
Titel	Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994
Redacteuren	D.W. Slocum
Plaats van productie	New York
Uitgeverij	Plenum Press
Pagina's	59-69
ISBN van geprinte versie	0-306-45212-X
Status	Gepubliceerd - 1995
Evenement	conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17 - Duur: 13 mrt 1994 → 17 mrt 1994

Congres

Congres	conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17
Periode	13/03/94 → 17/03/94
Ander	American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17

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Citeer dit

Cunningham, R. H., Santen, van, R. A., Mangnus, A. V. G., & Hoebink, J. H. B. J. (1995). Homologation reactions of alkanes on transition-metal surfaces. In D. W. Slocum (editor), Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994 (blz. 59-69). Plenum Press.

Cunningham, R.H. ; Santen, van, R.A. ; Mangnus, A.V.G. ; Hoebink, J.H.B.J. / Homologation reactions of alkanes on transition-metal surfaces. Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994. redacteur / D.W. Slocum. New York : Plenum Press, 1995. blz. 59-69

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title = "Homologation reactions of alkanes on transition-metal surfaces",

abstract = "A symposia; a combination of expts. using TAP, and isotopic labeling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temp. CO or CH4 adsorption was shown to be more likely at high temps., and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso-ratio between labeled and non-labeled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane",

author = "R.H. Cunningham and {Santen, van}, R.A. and A.V.G. Mangnus and J.H.B.J. Hoebink",

year = "1995",

language = "English",

isbn = "0-306-45212-X",

pages = "59--69",

editor = "D.W. Slocum",

booktitle = "Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994",

publisher = "Plenum Press",

address = "United States",

note = "conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17 ; Conference date: 13-03-1994 Through 17-03-1994",

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Cunningham, RH, Santen, van, RA, Mangnus, AVG & Hoebink, JHBJ 1995, Homologation reactions of alkanes on transition-metal surfaces. in DW Slocum (redactie), Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994. Plenum Press, New York, blz. 59-69, conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17, 13/03/94.

Homologation reactions of alkanes on transition-metal surfaces. / Cunningham, R.H.; Santen, van, R.A.; Mangnus, A.V.G.; Hoebink, J.H.B.J.

Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994. redactie / D.W. Slocum. New York : Plenum Press, 1995. blz. 59-69.

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/Congresprocedure › Conferentiebijdrage › Academic › peer review

TY - GEN

T1 - Homologation reactions of alkanes on transition-metal surfaces

AU - Cunningham, R.H.

AU - Santen, van, R.A.

AU - Mangnus, A.V.G.

AU - Hoebink, J.H.B.J.

PY - 1995

Y1 - 1995

N2 - A symposia; a combination of expts. using TAP, and isotopic labeling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temp. CO or CH4 adsorption was shown to be more likely at high temps., and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso-ratio between labeled and non-labeled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane

AB - A symposia; a combination of expts. using TAP, and isotopic labeling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temp. CO or CH4 adsorption was shown to be more likely at high temps., and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso-ratio between labeled and non-labeled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane

M3 - Conference contribution

SN - 0-306-45212-X

SP - 59

EP - 69

BT - Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994

A2 - Slocum, D.W.

PB - Plenum Press

CY - New York

T2 - conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17

Y2 - 13 March 1994 through 17 March 1994

ER -