Samenvatting
A symposia; a combination of expts. using TAP, and isotopic labeling of hydrocarbons using 11C over metal catalysts has provided useful information about the formation of carbon surface species and their activity. The formation of non-reactive surface species following high temp. CO or CH4 adsorption was shown to be more likely at high temps., and that this was a fairly rapid process. The activation energy for C-C coupling reactions was found to be higher following promotion of a Ru catalyst with V. Differences in n-/iso-ratio between labeled and non-labeled products indicated that different reaction pathways led to the formation of n-hexane and iso-hexane
| Originele taal-2 | Engels |
|---|---|
| Titel | Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994 |
| Redacteuren | D.W. Slocum |
| Plaats van productie | New York |
| Uitgeverij | Plenum Press |
| Pagina's | 59-69 |
| ISBN van geprinte versie | 0-306-45212-X |
| Status | Gepubliceerd - 1995 |
| Evenement | conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17 - Duur: 13 mrt 1994 → 17 mrt 1994 |
Congres
| Congres | conference; American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17; 1994-03-13; 1994-03-17 |
|---|---|
| Periode | 13/03/94 → 17/03/94 |
| Ander | American Chemical Society Symposium on Methane and Alkane Conversion Chemistry ; (San Diego, Calif.) : 1994.03.13.-17 |
Vingerafdruk Duik in de onderzoeksthema's van 'Homologation reactions of alkanes on transition-metal surfaces'. Samen vormen ze een unieke vingerafdruk.
Citeer dit
Cunningham, R. H., Santen, van, R. A., Mangnus, A. V. G., & Hoebink, J. H. B. J. (1995). Homologation reactions of alkanes on transition-metal surfaces. In D. W. Slocum (editor), Methane and Alkane Conversion Chemistry, [Proceedings of American Chemical Society Symposium on Methane and Alkane Conversion Chemistry], San Diego, Mar. 13-17, 1994 (blz. 59-69). New York: Plenum Press.