Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

P. Schipper; W.A.M. Castenmiller; J.W. Haan, de; H.M. Buck

doi:10.1039/c39730000574

Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

P. Schipper
, W.A.M. Castenmiller
, J.W. Haan, de
, H.M. Buck

Chemical Engineering and Chemistry

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

4 Citaten (Scopus)

227 Downloads (Pure)

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While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.

Originele taal-2	Engels
Pagina's (van-tot)	574-575
Tijdschrift	Journal of the Chemical Society, Chemical Communications
Nummer van het tijdschrift	16
DOI's	https://doi.org/10.1039/c39730000574
Status	Gepubliceerd - 1973

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title = "Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication",

abstract = "While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.",

author = "P. Schipper and W.A.M. Castenmiller and \{Haan, de\}, J.W. and H.M. Buck",

year = "1973",

doi = "10.1039/c39730000574",

language = "English",

pages = "574--575",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

AU - Schipper, P.

AU - Castenmiller, W.A.M.

AU - Haan, de, J.W.

AU - Buck, H.M.

PY - 1973

Y1 - 1973

N2 - While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.

AB - While the norbornen-7-ylium cation dissolved in liquid SO2 does not undergo 7-substitution with PPh3, the analogous reaction with the 7-methoxynorbornen-7-ylium cation produces the 7-methoxynorbornen-7-yl-triphenylphosphonium cation; the intermediate 7-triphenylphosphonio-norbornen-7-ylium dication could be detected.

U2 - 10.1039/c39730000574

DO - 10.1039/c39730000574

M3 - Article

SN - 0022-4936

SP - 574

EP - 575

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Formation of the 7-triphenylphosphonio-norbornen-7-ylium dication : a non-classical dication

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