Samenvatting
Exciton dynamics in chiral helixes of an oligo-p-phenylenevinylene deriv. monofunctionalized with a ureido-s-triazine (MOPV) were studied. The latter functional group leads to oligomer dimerization by hydrogen bonding in dodecane soln., resulting in reversible supramol. assembly by solvophobic and p-p interactions. MOPV is a model system to study exciton transfer dynamics as it is possible to study the effect of intermol. interactions by comparing optical properties in the dissolved phase (above the transition temp.) and the supramol. assemblies. The model allows to ext. microscopic informations such as the av. exciton hopping annihilation rates. It is believed that this model also allows the quant. description of the exciton dynamics on supramol. architectures from subpicosecond to nanosecond timescales.
Originele taal-2 | Engels |
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Titel | Ultrafast phenomena XIV : proceedings of the 14th international conference, Niigata, Japan, July 25 - 30, 2004 |
Redacteuren | T. Kobayashi, Y. Okada, K.A. Nelson, S. Silvestri, de |
Plaats van productie | Berlin |
Uitgeverij | Springer |
Pagina's | 281-283 |
ISBN van geprinte versie | 3-540-24110-8 |
DOI's | |
Status | Gepubliceerd - 2005 |
Evenement | 14th International Conference on Ultrafast Phenomena - Niigata, Japan Duur: 25 jul. 2004 → 30 jul. 2004 Congresnummer: 14 |
Publicatie series
Naam | Springer Series in Chemical Physics |
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Volume | 79 |
ISSN van geprinte versie | 0172-6218 |
Congres
Congres | 14th International Conference on Ultrafast Phenomena |
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Land/Regio | Japan |
Stad | Niigata |
Periode | 25/07/04 → 30/07/04 |
Ander | International Conference on Ultrafast Phenomena ; 14 (Niigata) |