Exciton diffusion dynamics in an organic semiconductor nanostructure

C. Daniel, L.M. Herz, S. Westenhoff, F. Makereel, D. Beljonne, F.J.M. Hoeben, P. Jonkheijm, A.P.H.J. Schenning, E.W. Meijer, C. Silva

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Samenvatting

Exciton dynamics in chiral helixes of an oligo-p-phenylenevinylene deriv. monofunctionalized with a ureido-s-triazine (MOPV) were studied. The latter functional group leads to oligomer dimerization by hydrogen bonding in dodecane soln., resulting in reversible supramol. assembly by solvophobic and p-p interactions. MOPV is a model system to study exciton transfer dynamics as it is possible to study the effect of intermol. interactions by comparing optical properties in the dissolved phase (above the transition temp.) and the supramol. assemblies. The model allows to ext. microscopic informations such as the av. exciton hopping annihilation rates. It is believed that this model also allows the quant. description of the exciton dynamics on supramol. architectures from subpicosecond to nanosecond timescales.
Originele taal-2Engels
TitelUltrafast phenomena XIV : proceedings of the 14th international conference, Niigata, Japan, July 25 - 30, 2004
RedacteurenT. Kobayashi, Y. Okada, K.A. Nelson, S. Silvestri, de
Plaats van productieBerlin
UitgeverijSpringer
Pagina's281-283
ISBN van geprinte versie3-540-24110-8
DOI's
StatusGepubliceerd - 2005
Evenement14th International Conference on Ultrafast Phenomena - Niigata, Japan
Duur: 25 jul. 200430 jul. 2004
Congresnummer: 14

Publicatie series

NaamSpringer Series in Chemical Physics
Volume79
ISSN van geprinte versie0172-6218

Congres

Congres14th International Conference on Ultrafast Phenomena
Land/RegioJapan
StadNiigata
Periode25/07/0430/07/04
AnderInternational Conference on Ultrafast Phenomena ; 14 (Niigata)

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