Energy-efficient solar photochemistry with luminescent solar concentrator based photomicroreactors

Dario Cambié, Jeroen Dobbelaar, Paola Riente, Jochen Vanderspikken, Chong Shen, Peter H. Seeberger, Kerry Gilmore, Michael G. Debije, Timothy Noël (Corresponding author)

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

34 Citaten (Scopus)
37 Downloads (Pure)

Samenvatting

The sun is the most sustainable light source available on our planet, therefore the direct use of sunlight for photochemistry is extremely appealing. Demonstrated here, for the first time, is that a diverse set of photon-driven transformations can be efficiently powered by solar irradiation with the use of solvent-resistant and cheap luminescent solar concentrator based photomicroreactors. Blue, green, and red reactors can accommodate both homogeneous and multiphase reaction conditions, including photochemical oxidations, photocatalytic trifluoromethylation chemistry, and metallaphotoredox transformations, thus spanning applications over the entire visible-light spectrum. To further illustrate the efficacy of these novel solar reactors, medicinally relevant molecules, such as ascaridole and an intermediate of artemisinin, were prepared as well.

Originele taal-2Engels
Pagina's (van-tot)14512-14516
Aantal pagina's5
TijdschriftAngewandte Chemie - International Edition
Volume58
Nummer van het tijdschrift40
DOI's
StatusGepubliceerd - 1 okt 2019

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