Electronic modifictions in supported palladium catalysts

B.L. Mojet, M.J. Kappers, J.C. Muijsers, J.W. Niemantsverdriet, J.T. Miller, F.S. Modica, D.C. Koningsberger

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review

42 Citaten (Scopus)

Samenvatting

XPS and IR spectroscopy indicate that the electron density of the supported metal clusters in Pd/LTL catalysts is a function of the support acidity/alkalinity. In addition, the neopentane and propane hydrogenolysis TOF's increase with increasing support acidity from alkaline to acidic. The changes in spectroscopic and catalytic properties are due to electron deficient Pd on acidic supports, as previously proposed, and electron rich Pd on alkaline supports.
Originele taal-2Engels
TitelZeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994
RedacteurenJ. Weitkamp, H. Karge, H. Pfeifer, W. Hölderich
Plaats van productieAmsterdam
UitgeverijElsevier
Pagina's909-
ISBN van geprinte versie0-444-81847-2
DOI's
StatusGepubliceerd - 1994
Evenementconference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22 -
Duur: 17 jul 199422 jul 1994

Publicatie series

NaamStudies in Surface Science and Catalysis
Volume84
ISSN van geprinte versie0167-2991

Congres

Congresconference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22
Periode17/07/9422/07/94
AnderIZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22

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  • Citeer dit

    Mojet, B. L., Kappers, M. J., Muijsers, J. C., Niemantsverdriet, J. W., Miller, J. T., Modica, F. S., & Koningsberger, D. C. (1994). Electronic modifictions in supported palladium catalysts. In J. Weitkamp, H. Karge, H. Pfeifer, & W. Hölderich (editors), Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994 (blz. 909-). (Studies in Surface Science and Catalysis; Vol. 84). Elsevier. https://doi.org/10.1016/S0167-2991(08)63623-X