Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

E. Peeters; R.A.J. Janssen; E.W. Meijer

doi:10.1016/S0379-6779(98)01388-5

Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

Materials to Optoelectronic Devices

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A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films

Originele taal-2	Engels
Pagina's (van-tot)	1105-1106
Aantal pagina's	2
Tijdschrift	Synthetic Metals
Volume	102
Nummer van het tijdschrift	1-3
DOI's	https://doi.org/10.1016/S0379-6779(98)01388-5
Status	Gepubliceerd - 1999

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10.1016/S0379-6779(98)01388-5

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title = "Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)",

abstract = "A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films",

author = "E. Peeters and R.A.J. Janssen and E.W. Meijer",

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AB - A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films

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DO - 10.1016/S0379-6779(98)01388-5

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Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

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