Effect of initiation on atom transfer radical copolymerization

B. Klumperman, G. Chambard

Onderzoeksoutput: Hoofdstuk in Boek/Rapport/CongresprocedureConferentiebijdrageAcademicpeer review


Based on published results it is obvious that apparent reactivity ratios in atom transfer radical copolymn. (ATRcP) differ slightly, but significantly from those in the free radical copolymn. (FRcP). With the aid of simulations and dedicated expts. we were able to assign these differences to differences in rate of primary radical addn. to the two comonomers in ATRcP.At the onset of polymn. there may be large fluctuations in propagating radical ratio when ATRcP is carried out. The result of this phenomenon on the detn. of reactivity ratio is discussed, and an alternative method for the exptl. assessment of reactivity ratios is proposed
Originele taal-2Engels
TitelAbstracts of Papers, 224th ACS National Meeting, Boston, MA, United States, August 18-22, 2002
Plaats van productieWashington, D. C
UitgeverijAmerican Chemical Society
StatusGepubliceerd - 2002
Evenement224th ACS National Meeting - Boston, Verenigde Staten van Amerika
Duur: 18 aug. 200222 aug. 2002


Congres224th ACS National Meeting
Land/RegioVerenigde Staten van Amerika
Ander224th ACS National Meeting, Fall meeting, Boston, MA, United States, August 18-22, 2002


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