Development of thin PdeAg supported membranes for fluidized bed membrane reactors including WGS related gases

E. Fernandez Gesalaga, A. Helmi Siasi Farimani, K.T. Coenen, J. Melendez, J.L Viviente, D.A. Pacheco Tanaka, M. Sint Annaland, van, F. Gallucci

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Uittreksel

This paper reports the preparation, characterization and stability tests of Pd-based thin membranes for fluidized bed membrane reactor applications. Various thin membranes have been prepared by simultaneous Pd–Ag electroless plating. A simple technique for sealing of the produced membranes is reported and discussed. The membranes have been characterized for single gas permeation, and afterwards used for permeation of mixtures of gases and under fluidization conditions. The membranes have shown very high permeation rates and perm-selectivity when used as permeators. When applied in fluidized bed reactors it has been found that the membranes are stable as long as no interaction between the fluidization catalyst and the membrane surface occurs. For some catalysts a strong chemical interaction between the catalyst and the membrane surface has been observed which caused a drastic decrease in the membrane flux.
TaalEngels
Pagina's3506-3519
TijdschriftInternational Journal of Hydrogen Energy
Volume40
Nummer van het tijdschrift8
DOI's
StatusGepubliceerd - 2015

Vingerafdruk

Fluidized beds
beds
reactors
membranes
Membranes
Gases
gases
Permeation
Fluidization
catalysts
Catalysts
stability tests
Electroless plating
sealing
plating
selectivity
interactions
Fluxes
preparation

Citeer dit

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title = "Development of thin PdeAg supported membranes for fluidized bed membrane reactors including WGS related gases",
abstract = "This paper reports the preparation, characterization and stability tests of Pd-based thin membranes for fluidized bed membrane reactor applications. Various thin membranes have been prepared by simultaneous Pd–Ag electroless plating. A simple technique for sealing of the produced membranes is reported and discussed. The membranes have been characterized for single gas permeation, and afterwards used for permeation of mixtures of gases and under fluidization conditions. The membranes have shown very high permeation rates and perm-selectivity when used as permeators. When applied in fluidized bed reactors it has been found that the membranes are stable as long as no interaction between the fluidization catalyst and the membrane surface occurs. For some catalysts a strong chemical interaction between the catalyst and the membrane surface has been observed which caused a drastic decrease in the membrane flux.",
author = "{Fernandez Gesalaga}, E. and {Helmi Siasi Farimani}, A. and K.T. Coenen and J. Melendez and J.L Viviente and {Pacheco Tanaka}, D.A. and {Sint Annaland, van}, M. and F. Gallucci",
year = "2015",
doi = "10.1016/j.ijhydene.2014.08.074",
language = "English",
volume = "40",
pages = "3506--3519",
journal = "International Journal of Hydrogen Energy",
issn = "0360-3199",
publisher = "Elsevier",
number = "8",

}

Development of thin PdeAg supported membranes for fluidized bed membrane reactors including WGS related gases. / Fernandez Gesalaga, E.; Helmi Siasi Farimani, A.; Coenen, K.T.; Melendez, J.; Viviente, J.L; Pacheco Tanaka, D.A.; Sint Annaland, van, M.; Gallucci, F.

In: International Journal of Hydrogen Energy, Vol. 40, Nr. 8, 2015, blz. 3506-3519.

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

TY - JOUR

T1 - Development of thin PdeAg supported membranes for fluidized bed membrane reactors including WGS related gases

AU - Fernandez Gesalaga,E.

AU - Helmi Siasi Farimani,A.

AU - Coenen,K.T.

AU - Melendez,J.

AU - Viviente,J.L

AU - Pacheco Tanaka,D.A.

AU - Sint Annaland, van,M.

AU - Gallucci,F.

PY - 2015

Y1 - 2015

N2 - This paper reports the preparation, characterization and stability tests of Pd-based thin membranes for fluidized bed membrane reactor applications. Various thin membranes have been prepared by simultaneous Pd–Ag electroless plating. A simple technique for sealing of the produced membranes is reported and discussed. The membranes have been characterized for single gas permeation, and afterwards used for permeation of mixtures of gases and under fluidization conditions. The membranes have shown very high permeation rates and perm-selectivity when used as permeators. When applied in fluidized bed reactors it has been found that the membranes are stable as long as no interaction between the fluidization catalyst and the membrane surface occurs. For some catalysts a strong chemical interaction between the catalyst and the membrane surface has been observed which caused a drastic decrease in the membrane flux.

AB - This paper reports the preparation, characterization and stability tests of Pd-based thin membranes for fluidized bed membrane reactor applications. Various thin membranes have been prepared by simultaneous Pd–Ag electroless plating. A simple technique for sealing of the produced membranes is reported and discussed. The membranes have been characterized for single gas permeation, and afterwards used for permeation of mixtures of gases and under fluidization conditions. The membranes have shown very high permeation rates and perm-selectivity when used as permeators. When applied in fluidized bed reactors it has been found that the membranes are stable as long as no interaction between the fluidization catalyst and the membrane surface occurs. For some catalysts a strong chemical interaction between the catalyst and the membrane surface has been observed which caused a drastic decrease in the membrane flux.

U2 - 10.1016/j.ijhydene.2014.08.074

DO - 10.1016/j.ijhydene.2014.08.074

M3 - Article

VL - 40

SP - 3506

EP - 3519

JO - International Journal of Hydrogen Energy

T2 - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

SN - 0360-3199

IS - 8

ER -