Development of highly permeable ultra-thin Pd-bases supported membranes

E. Fernandez; J.A. Sanchez-Garcia; Jon Melendez Rey; V. Spallina; M. van Sint Annaland; F. Gallucci; D.A. Pacheco Tanaka; R. Prema

doi:10.1016/j.cej.2015.11.060

Development of highly permeable ultra-thin Pd-bases supported membranes

E. Fernandez, J.A. Sanchez-Garcia, Jon Melendez Rey, V. Spallina, M. van Sint Annaland, F. Gallucci, D.A. Pacheco Tanaka, R. Prema

Chemical Process Intensification

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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This paper reports the preparation and characterization of ultra-thin (∼1 μm thick) Pd-based supported membranes for hydrogen purification. Ultra-thin membranes have been prepared by a combination of PVD magnetron sputtering and electroless plating techniques. The membranes have been characterized for single gas and mix gas permeation at temperatures between 350 and 500 °C and they have shown to exhibit very high hydrogen fluxes combined with a good perm-selectivity (H2/N2 ≈ 500). These results have been compared with the performance of highly permeable membranes reported in the literature. The influence of the morphology of the deposited Pd-based layers on the membrane performance has been investigated and discussed.

Originele taal-2	Engels
Pagina's (van-tot)	149-155
Aantal pagina's	7
Tijdschrift	Chemical Engineering Journal
Volume	305
Vroegere onlinedatum	23 nov 2015
DOI's	https://doi.org/10.1016/j.cej.2015.11.060
Status	Gepubliceerd - 24 okt 2016

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title = "Development of highly permeable ultra-thin Pd-bases supported membranes",

abstract = "This paper reports the preparation and characterization of ultra-thin (∼1 μm thick) Pd-based supported membranes for hydrogen purification. Ultra-thin membranes have been prepared by a combination of PVD magnetron sputtering and electroless plating techniques. The membranes have been characterized for single gas and mix gas permeation at temperatures between 350 and 500 °C and they have shown to exhibit very high hydrogen fluxes combined with a good perm-selectivity (H2/N2 ≈ 500). These results have been compared with the performance of highly permeable membranes reported in the literature. The influence of the morphology of the deposited Pd-based layers on the membrane performance has been investigated and discussed.",

keywords = "membranes, Palladium membrane preparation, PVD magnetron sputtering, ELP, H2 separation, Ultra-thin layer",

author = "E. Fernandez and J.A. Sanchez-Garcia and {Melendez Rey}, Jon and V. Spallina and {van Sint Annaland}, M. and F. Gallucci and {Pacheco Tanaka}, D.A. and R. Prema",

year = "2016",

month = oct,

day = "24",

doi = "10.1016/j.cej.2015.11.060",

language = "English",

volume = "305",

pages = "149--155",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

publisher = "Elsevier",

}

Development of highly permeable ultra-thin Pd-bases supported membranes. / Fernandez, E.; Sanchez-Garcia, J.A.; Melendez Rey, Jon; Spallina, V.; van Sint Annaland, M.; Gallucci, F.; Pacheco Tanaka, D.A.; Prema, R.

In: Chemical Engineering Journal, Vol. 305, 24.10.2016, blz. 149-155.

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

TY - JOUR

T1 - Development of highly permeable ultra-thin Pd-bases supported membranes

AU - Fernandez, E.

AU - Sanchez-Garcia, J.A.

AU - Melendez Rey, Jon

AU - Spallina, V.

AU - van Sint Annaland, M.

AU - Gallucci, F.

AU - Pacheco Tanaka, D.A.

AU - Prema, R.

PY - 2016/10/24

Y1 - 2016/10/24

N2 - This paper reports the preparation and characterization of ultra-thin (∼1 μm thick) Pd-based supported membranes for hydrogen purification. Ultra-thin membranes have been prepared by a combination of PVD magnetron sputtering and electroless plating techniques. The membranes have been characterized for single gas and mix gas permeation at temperatures between 350 and 500 °C and they have shown to exhibit very high hydrogen fluxes combined with a good perm-selectivity (H2/N2 ≈ 500). These results have been compared with the performance of highly permeable membranes reported in the literature. The influence of the morphology of the deposited Pd-based layers on the membrane performance has been investigated and discussed.

AB - This paper reports the preparation and characterization of ultra-thin (∼1 μm thick) Pd-based supported membranes for hydrogen purification. Ultra-thin membranes have been prepared by a combination of PVD magnetron sputtering and electroless plating techniques. The membranes have been characterized for single gas and mix gas permeation at temperatures between 350 and 500 °C and they have shown to exhibit very high hydrogen fluxes combined with a good perm-selectivity (H2/N2 ≈ 500). These results have been compared with the performance of highly permeable membranes reported in the literature. The influence of the morphology of the deposited Pd-based layers on the membrane performance has been investigated and discussed.

KW - membranes

KW - Palladium membrane preparation

KW - PVD magnetron sputtering

KW - ELP

KW - H2 separation

KW - Ultra-thin layer

U2 - 10.1016/j.cej.2015.11.060

DO - 10.1016/j.cej.2015.11.060

M3 - Article

VL - 305

SP - 149

EP - 155

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

SN - 1385-8947

ER -