Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts

Y. Guan; Y. Li; R.A. Santen, van; E.J.M. Hensen; Can Li

doi:10.1007/s10562-007-9151-4

Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts

Y. Guan, Y. Li, R.A. Santen, van, E.J.M. Hensen, Can Li

Inorganic Materials & Catalysis

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

28 Citaten (Scopus)

1 Downloads (Pure)

Samenvatting

The iron location in FeSBA-15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. At low iron loading, Fe is present as isolated species in the amorphous silica phase. At higher loading additional aggregated forms of iron oxide exist. Isolated species in the silica matrix imply Brønsted acidity resulting in selective formation of ethylene, whereas clusters catalyze formation of ethylene and aldehyde

Originele taal-2	Engels
Pagina's (van-tot)	18-24
Tijdschrift	Catalysis Letters
Volume	117
Nummer van het tijdschrift	1-2
DOI's	https://doi.org/10.1007/s10562-007-9151-4
Status	Gepubliceerd - 2007

Toegang tot document

10.1007/s10562-007-9151-4

Citeer dit

@article{239bfbffd0734475a95db783d92d3d80,

title = "Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts",

abstract = "The iron location in FeSBA-15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. At low iron loading, Fe is present as isolated species in the amorphous silica phase. At higher loading additional aggregated forms of iron oxide exist. Isolated species in the silica matrix imply Br{\o}nsted acidity resulting in selective formation of ethylene, whereas clusters catalyze formation of ethylene and aldehyde",

author = "Y. Guan and Y. Li and {Santen, van}, R.A. and E.J.M. Hensen and Can Li",

year = "2007",

doi = "10.1007/s10562-007-9151-4",

language = "English",

volume = "117",

pages = "18--24",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "1-2",

}

TY - JOUR

T1 - Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts

AU - Guan, Y.

AU - Li, Y.

AU - Santen, van, R.A.

AU - Hensen, E.J.M.

AU - Li, Can

PY - 2007

Y1 - 2007

N2 - The iron location in FeSBA-15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. At low iron loading, Fe is present as isolated species in the amorphous silica phase. At higher loading additional aggregated forms of iron oxide exist. Isolated species in the silica matrix imply Brønsted acidity resulting in selective formation of ethylene, whereas clusters catalyze formation of ethylene and aldehyde

AB - The iron location in FeSBA-15 strongly influences the selectivity to dehydrogenation and dehydration in ethanol conversion. At low iron loading, Fe is present as isolated species in the amorphous silica phase. At higher loading additional aggregated forms of iron oxide exist. Isolated species in the silica matrix imply Brønsted acidity resulting in selective formation of ethylene, whereas clusters catalyze formation of ethylene and aldehyde

U2 - 10.1007/s10562-007-9151-4

DO - 10.1007/s10562-007-9151-4

M3 - Article

SN - 1011-372X

VL - 117

SP - 18

EP - 24

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

Controlling reaction pathways for alcohol dehydration and dehydrogenation over FeSBA-15 catalysts

Samenvatting

Toegang tot document

Vingerafdruk

Citeer dit