Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes

H. Nowothnick; A. Rost; T. Hamerla; R. Schomäcker; C. Müller; D. Vogt

doi:10.1039/C2CY20629C

Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes

H. Nowothnick
, A. Rost
, T. Hamerla
, R. Schomäcker
, C. Müller
, D. Vogt

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

45 Citaten (Scopus)

4 Downloads (Pure)

Samenvatting

The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand SulfoXantPhos was investigated for different phase transfer agents (PTA). As such, polymer latices and microemulsions formed by non-ionic surfactants were used. In general, a higher PTA concentration enhances the reaction progress. The feasibility of catalyst recycling by simple phase separation is shown in principle. The Rh losses are low in the surfactant system and promising for a technical approach.

Originele taal-2	Engels
Pagina's (van-tot)	600-605
Aantal pagina's	6
Tijdschrift	Catalysis Science & Technology
Volume	2013
Nummer van het tijdschrift	3
DOI's	https://doi.org/10.1039/C2CY20629C
Status	Gepubliceerd - 2013

Toegang tot document

10.1039/C2CY20629C

Citeer dit

@article{07142dbdd0bc42539a9aa68531660dc2,

title = "Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes",

abstract = "The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand SulfoXantPhos was investigated for different phase transfer agents (PTA). As such, polymer latices and microemulsions formed by non-ionic surfactants were used. In general, a higher PTA concentration enhances the reaction progress. The feasibility of catalyst recycling by simple phase separation is shown in principle. The Rh losses are low in the surfactant system and promising for a technical approach.",

author = "H. Nowothnick and A. Rost and T. Hamerla and R. Schom{\"a}cker and C. M{\"u}ller and D. Vogt",

year = "2013",

doi = "10.1039/C2CY20629C",

language = "English",

volume = "2013",

pages = "600--605",

journal = "Catalysis Science \& Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "3",

}

TY - JOUR

T1 - Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes

AU - Nowothnick, H.

AU - Rost, A.

AU - Hamerla, T.

AU - Schomäcker, R.

AU - Müller, C.

AU - Vogt, D.

PY - 2013

Y1 - 2013

N2 - The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand SulfoXantPhos was investigated for different phase transfer agents (PTA). As such, polymer latices and microemulsions formed by non-ionic surfactants were used. In general, a higher PTA concentration enhances the reaction progress. The feasibility of catalyst recycling by simple phase separation is shown in principle. The Rh losses are low in the surfactant system and promising for a technical approach.

AB - The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand SulfoXantPhos was investigated for different phase transfer agents (PTA). As such, polymer latices and microemulsions formed by non-ionic surfactants were used. In general, a higher PTA concentration enhances the reaction progress. The feasibility of catalyst recycling by simple phase separation is shown in principle. The Rh losses are low in the surfactant system and promising for a technical approach.

U2 - 10.1039/C2CY20629C

DO - 10.1039/C2CY20629C

M3 - Article

SN - 2044-4753

VL - 2013

SP - 600

EP - 605

JO - Catalysis Science & Technology

JF - Catalysis Science & Technology

IS - 3

ER -

Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes

Samenvatting

Toegang tot document

Vingerafdruk

Citeer dit