Commensurate freezing of n-Alkanes in silicalite

W.J.M. van Well; J.P. Wolthuizen; B. Smit; J.H.C. Hooff, van; R.A. Santen, van

doi:10.1002/anie.199525431

Commensurate freezing of n-Alkanes in silicalite

W.J.M. van Well
, J.P. Wolthuizen
, B. Smit
, J.H.C. Hooff, van
, R.A. Santen, van

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.

Originele taal-2	Engels
Pagina's (van-tot)	2543-2544
Aantal pagina's	2
Tijdschrift	Angewandte Chemie - International Edition
Volume	34
Nummer van het tijdschrift	22
DOI's	https://doi.org/10.1002/anie.199525431
Status	Gepubliceerd - 1995

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title = "Commensurate freezing of n-Alkanes in silicalite",

abstract = "Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.",

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AU - van Well, W.J.M.

AU - Wolthuizen, J.P.

AU - Smit, B.

AU - Hooff, van, J.H.C.

AU - Santen, van, R.A.

PY - 1995

Y1 - 1995

N2 - Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.

AB - Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.

U2 - 10.1002/anie.199525431

DO - 10.1002/anie.199525431

M3 - Article

SN - 1433-7851

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

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Commensurate freezing of n-Alkanes in silicalite

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