Combination of supramolecular cross-linking with covalent cross-linking through epoxide ring-opening including gel studies

H. Hofmeier, A. El-Ghayoury, U.S. Schubert

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

Samenvatting

Terpolymers based on poly(methyl methacrylate), containing terpyridine-moieties as well as epoxide groups, were synthesized via free-radical polymeri-zation. The products were cross-linked non-covalently with iron(II) ions and cova-lently by treatment with AlCl3. Both steps could be combined in different order. The non-covalent cross-linking could be reversed by applying a strong competing ligand. The swelling behaviour of the polymers was investigated.
Originele taal-2Engels
Artikelnummer053
Pagina's (van-tot)053-1/13
Tijdschrifte-Polymers
Volume2003
StatusGepubliceerd - 2003

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