Chirality due to oxygen-18 substitution. Synthesis and chiroptical properties of (1S)-2,4-adamantanedione-4-18O

E.W. Meijer; H. Wynberg

doi:10.1021/ja00368a061

Chirality due to oxygen-18 substitution. Synthesis and chiroptical properties of (1S)-2,4-adamantanedione-4-18O

E.W. Meijer, H. Wynberg

Macromolecular and Organic Chemistry

Onderzoeksoutput: Bijdrage aan tijdschrift › Tijdschriftartikel › Academic › peer review

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Optically active (1S)-2,4-adamantanedione-4-18O (I) was prepd. by the route for chiral adamantanones. The 18O label is introduced in the final step by thermal decompn. of the 1,2-dioxetane-18O, prepd. by irradiating an enol ether in an atm. of 18O. The CD spectrum of I shows several bands of large amplitude. [on SciFinder (R)]

Originele taal-2	Engels
Pagina's (van-tot)	1145-1146
Tijdschrift	Journal of the American Chemical Society
Volume	104
Nummer van het tijdschrift	4
DOI's	https://doi.org/10.1021/ja00368a061
Status	Gepubliceerd - 1982

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title = "Chirality due to oxygen-18 substitution. Synthesis and chiroptical properties of (1S)-2,4-adamantanedione-4-18O",

abstract = "Optically active (1S)-2,4-adamantanedione-4-18O (I) was prepd. by the route for chiral adamantanones. The 18O label is introduced in the final step by thermal decompn. of the 1,2-dioxetane-18O, prepd. by irradiating an enol ether in an atm. of 18O. The CD spectrum of I shows several bands of large amplitude. [on SciFinder (R)]",

author = "E.W. Meijer and H. Wynberg",

year = "1982",

doi = "10.1021/ja00368a061",

language = "English",

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journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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AU - Meijer, E.W.

AU - Wynberg, H.

PY - 1982

Y1 - 1982

N2 - Optically active (1S)-2,4-adamantanedione-4-18O (I) was prepd. by the route for chiral adamantanones. The 18O label is introduced in the final step by thermal decompn. of the 1,2-dioxetane-18O, prepd. by irradiating an enol ether in an atm. of 18O. The CD spectrum of I shows several bands of large amplitude. [on SciFinder (R)]

AB - Optically active (1S)-2,4-adamantanedione-4-18O (I) was prepd. by the route for chiral adamantanones. The 18O label is introduced in the final step by thermal decompn. of the 1,2-dioxetane-18O, prepd. by irradiating an enol ether in an atm. of 18O. The CD spectrum of I shows several bands of large amplitude. [on SciFinder (R)]

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DO - 10.1021/ja00368a061

M3 - Article

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JF - Journal of the American Chemical Society

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Chirality due to oxygen-18 substitution. Synthesis and chiroptical properties of (1S)-2,4-adamantanedione-4-18O

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