Chiral excitonic organic photodiodes for direct detection of circular polarized light

Matthias Schulz, Frank Balzer, Dorothea Scheunemann, Oriol Arteaga, Arne Lützen, Stefan C.J. Meskers, Manuela Schiek (Corresponding author)

Onderzoeksoutput: Bijdrage aan tijdschriftTijdschriftartikelAcademicpeer review

81 Citaten (Scopus)
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A facile route to soft matter self-powered bulk heterojunction photodiode detectors sensitive to the circular polarization state of light is shown based on the intrinsic excitonic circular dichroism of the photoactive layer blend. As light detecting materials, enantiopure semiconducting small molecular squaraine derivates of opposite handedness are employed. Via Mueller matrix ellipsometry, the circular dichroism is proven to be of H-type excitonic nature and not originating from mesoscopic structural ordering. Within the green spectral range, the photodiodes convert circular polarized light into a handedness-dependent photocurrent with a maximum dissymmetry factor of ±0.1 corresponding to 5% overall efficiency for the polarization discrimination under short circuit conditions. On the basis of transfer matrix optical simulations, it is rationalized that the optical dissymmetry fully translates into a photocurrent dissymmetry for ease of device design. Thereby, the photodiode's ability to efficiently distinguish between left and right circularly polarized light without the use of external optical elements and voltage bias is demonstrated. This allows a straightforward and sustainable future design of flexible, lightweight, and compact integrated platforms for chiroptical imaging and sensing.

Originele taal-2Engels
Aantal pagina's7
TijdschriftAdvanced Functional Materials
Nummer van het tijdschrift16
Vroegere onlinedatum6 mrt. 2019
StatusGepubliceerd - 18 apr. 2019


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