Catalytic oxidative dehydrogenation of cyclohexene

R.A. Sheldon; J.M. Sobczak

doi:10.1016/0304-5102(91)80056-9

Catalytic oxidative dehydrogenation of cyclohexene

R.A. Sheldon, J.M. Sobczak

Chemical Engineering and Chemistry

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Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).

Originele taal-2	Engels
Pagina's (van-tot)	1-6
Aantal pagina's	6
Tijdschrift	Journal of Molecular Catalysis
Volume	68
Nummer van het tijdschrift	1
DOI's	https://doi.org/10.1016/0304-5102(91)80056-9
Status	Gepubliceerd - 1991

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title = "Catalytic oxidative dehydrogenation of cyclohexene",

abstract = "Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).",

author = "R.A. Sheldon and J.M. Sobczak",

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AU - Sheldon, R.A.

AU - Sobczak, J.M.

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N2 - Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).

AB - Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).

U2 - 10.1016/0304-5102(91)80056-9

DO - 10.1016/0304-5102(91)80056-9

M3 - Article

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JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

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Catalytic oxidative dehydrogenation of cyclohexene

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